FENG Huijuan;LYU Xinlei;Geology Bureau of Coal Resources,Coal Industry Office of Shanxi Province;In order to determine concomitant Li content accurately in coal and fly ash,the coal and fly ash samples were ashed at high temperature first,then the products was dissolved by nitric acid-hydrofluoric acid-perchloric acid ternary system,at last,the inductively coupled plasma-optical emission spectrometry( ICP-OES) was adopted to determine the Li content. The results showed that,the Li content could be determined accurately without matrix matching by optimizing decomposition method,RF power,observation height,analytical line and spectral and observation mode.The detection limits of coal and fly ash were 0. 01,0. 03 μg / g,the recovery rate of three coal samples whose Li content had a large different ranged from 92. 8% to 96. 0%.The method was verified by soil national standard reference materials of GB W07405,GB W07406 which were similar to the ash.The results were in agreement with the certified value,and the relative standard deviation( n = 12) was 0. 99%,0. 73% respectively.The method had the advantages of rapidity,simplicity and accuracy.
2016 06 v.22;No.106 [Abstract][OnlineView][Download 133K]