ZHAO Jiayun,ZHAO Yuewu(Kunming Institute of Coal Science,Kunming 650041,China)Through semi-coking experiments,analyse the basic properties of two kinds of high rank lignite from Yunnan Province.Determine the particle size of lignite in distillation zone range from 6mm to 25 mm.Investigate the pyrolysis characteristics of lignite by external heating devolatilization.The results show that,for lignite sample Ⅰ,the productive rate of semi-coke,tar,gas and thermal-water reach up to 49.42 percent,13.20 percent,8.56 percent and 24.18 percent.For lignite sample Ⅱ,they are 51.38 percent,15.36 percent,8.10 percent,23.27 percent.The higher the end devolatilization temperature,the greater the productive rate of dry gas and H2,while the yield of CO and CH4 is just the opposite.The calorific value of gas of these two samples generally remain at 14 MJ/m3 to 15 MJ/m3.At 800 ℃ coking temperature,the characteristics of semi-coke are comparatively good.The devolatilization index of sampleⅠis much better than that of sampleⅡ.The results show that,the semi-coke sampleⅠhas a series of advantages such as high calorific value,specific resistance,reactivity,well-developed porosity and low sulphur,ash content and aluminum-bearing,which can be used as carbon reductant for metallurgical electric furnace.The semi-coke sampleⅡhas similar quality index as the sampleⅠexcept higher ash content,and can be substituted for bituminite in the field of cement making,sugar refinery,flue-cured tobacco.
2013 03 v.19 [Abstract][OnlineView][Download 169K]