LI Gang~1,LING Kai-cheng~2 (1.School of Material and Chemical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China; 2.College of Chemistry and Chemical Engineering,Taiyuan University of Technology,Taiyuan 030024,China)Taking Yangcun coal as an example,the reactive characteristic of initial stage in direct coal liquefaction process was studied by using a 17mL micro-autoclave.Under the condition of 490℃ and double amount of tetralin solvent,the total conversion approached 84.47% when the reaction time was only 5 minutes,which showed that coal had an initial high reactivity characteristic in direct liquefaction process.Under pure N_2 atmosphere,the conversion increased from 66.38% to 83.27% as the initial pressure increased from 1.5 MPa to 7 MPa,which showed that besides the contribution to hydrogen-donation the pressure itself of H_2 pressure was also very important.Under 1.5 MPa of N_2 pressure,with the solvent/coal ratio was increased to 4:1,the conversion increased to 79%,but after that it did not increase any more,which showed that the method of adding excessive amount of hydrogen donor solvent to compensate the conversion loss brought by the decrease in system pressure was infeasible.
2010 06 v.16;No.70 [Abstract][OnlineView][Download 407K]