Status and suggestion of thermal fragmentation of low rank coal
CHANG Zhaogang;WANG Libin;PEI Xianfeng;ZHOU Qi;
Abstract:
In order to cleanly use lignite in large-scale,the status of fragmentation during thermal conversion of coal at home and abroad was analyzed.The fragmentation mechanism,the effects of coal quality and transformation conditions on fragmentation of coal were investigated.Due to the issue such as high content of dust in tar during the utilization of low rank coal,some solutions for inhibit pathway of thermal fragmentation were proposed.The fragmentation mechanism could be revealed by analyzing and regulating the physical and chemical properties of low rank coal and the transformation conditions.Based on the thermal reaction products,the relationship between fragmentation and heating process was established. The amount of dust could be decreased through exploiting new reactor which minimized the motion of coal particles.A technology approach for clean and efficient utilization of low rank coal was built.
Key Words: low rank coal;combustion;fragmentation;pulverization;dust
Foundation: 国家自然科学基金资助项目(21406105)
Authors: CHANG Zhaogang;WANG Libin;PEI Xianfeng;ZHOU Qi;
DOI: 10.13226/j.issn.1006-6772.2016.06.009
References:
- [1]Chirone R,Massimilla L.Primary fragmentation of coal in fluidized bed combustion[C]//22thSymposium on Combustion.Pittsburgh:The Combustion Institute,1988:267-279.
- [2]Sundback C A,Beer J M,Sarofim A F.Fragmentation behavior of single coal particle in a fluidized bed[C]//20thSymposium(International)on Combustion.Pittsburgh:The Combustion Institute,1984:1495-1503.
- [3]Chirone R,Massimilla L.Primary fragmentation in fluidized bed combustion of anthracites[J].Power Technology,1991,64(3):249-258.
- [4]Daki cˇD,Honing G,Valk M.Fragmentation and swelling of various coals during devolatilization in a fluidized bed[J].Fuel,1989,68(7):911-916.
- [5]Dacombe P,Pourkashanian M,Williams A,et al.Combustion-induced fragmentation behavior of isolated coal particles[J].Fuel,1999,78(15):1847-1857.
- [6]张宏焘.煤在流化床燃烧过程中的破碎特性及焦炭表面灰层扩散传质特性的研究[D].杭州:浙江大学,1990.
- [7]马利强,路霁鸰,岳光溪.流化床条件下煤的一次爆裂特性的实验研究[J].燃料化学学报,2000,28(1):44-48.Ma Liqiang,Lu Jiling,Yue Guangxi.Experimental study on primary fragmentation of coals in fluidized bed[J].Journal of Fuel Chemistry and Technology,2000,28(1):44-48.
- [8]吴正舜,刘欣,吴创之,等.煤在燃烧过程中的破碎[J].电站系统工程,2003,19(2):4-6.Wu Zhengshun,Liu Xin,Wu Chuangzhi,et al.The fragment of coal during combustion[J].Power System Engineering,2003,19(2):4-6.
- [9]Chirone R,Massimilla L,Salatino P.Comminution of carbons in fluidized bed combustion[J].Progress of Energy Combustion Science,1991,17(4):297-326.
- [10]Chirone R,Massimilla L.The application of weibull theory to primary fragmentation of coal during devolatilization[J].Power Technology,1989,57(3):197-212.
- [11]Marban G,Pis J J,Fuertes A B.Characterizing fuels for atmospheric fluidized bed combustion[J].Combustion and Flame,1995,103(1/2):41-58.
- [12]Fuertes A B,Marban G.Modelling gasification reactions including the percolation phenomenon[J].Chemical Engineering Science,1994,49(94):3813-3821.
- [13]Liu G,Wu H,Gupta R P,et al.Modeling the fragmentation of non-uniform porous char particles during pulverized coal combustion[J].Fuel,2000,79(6):627-633.
- [14]Beer J M,Kim J S,Kim J J.Comminution characteristics of Korean anthracite in a CFB reactor[J].Fuel,2003,82(11):1349-1357.
- [15]李爱民,池涌,严建华,等.大颗粒碳在流化床中燃烧的热应力破碎理论[J].煤炭学报,1998,23(2):208-211.Li Aimin,Chi Yong,Yan Jianhua,et al.A thermal stress breakage theory for large carbon particles during combustion in fluidized bed[J].Journal of China Coal Society,1998,23(2):208-211.
- [16]Zhang W N,Johnsson F,Leckner B.Fluid-dynamic boundary layers in CFB boilers[J].Chemical Engineering Science,1995,50(2):201-210.
- [17]姚海.流化床中煤颗粒热膨胀破碎特性的实验研究与定量评价[D].武汉:华中科技大学,2006.
- [18]Lee S H,Kim S D,Lee D H.Particle size reduction of anthracite coals during devolatilization in a thermobalance reactor[J].Fuel,2002,81(13):1633-1639.
- [19]黄建辉,徐明厚,于敦喜,等.煤燃烧过程中一次破碎的影响因素分析[J].工程热物理学报,2005,26(3):519-522.Huang Jianhui,Xu Minghou,Yu Dunxi,et al.Significant factors affecting the primary fragmentation of coal particles during coal combustion[J].Journal of Engineering Thermophysics,2005,26(3):519-522.
- [20]于敦喜,徐明厚,黄建辉,等.煤焦破碎成灰模型研究[J].工程热物理学报,2005,26(6):1041-1044.Yu Dunxi,Xu Minghou,Huang Jianhui,et al.A model study on char fragmentation and ash formation[J].Journal of Engineering Thermophysics,2005,26(6):1041-1044.
- [21]步学朋,陈家仁,彭万旺.高煤阶无烟煤热爆机理研究[J].煤炭学报,2000,25(S1):209-212.Bu Xuepeng,Chen Jiaren,Peng Wanwang.Study on thermal cracking of high rank anthracite[J].Journal of China Coal Society,2000,25(S1):209-212.
- [22]何宏舟.CFB锅炉洁净燃烧福建无烟煤的理论与试验研究[D].杭州:浙江大学,2005.
- [23]杨杰.燃煤一次破碎特性的实验研究[D].太原:太原理工大学,2012.
- [24]Chen W Y,Nagarajan G,Zhang Z P.Stochastic modeling of devolatilization-induced coal fragmentation during fluidized-bed combustion[J].Industrial&Engineering Chemistry Research,1994,33(1):137-145.
- [25]Cui Y B,Stuvbington J F.A mathematical model of in-bed char combustion of Australian coals in PFBC[J].Fuel,2001,80(14):2049-2056.
- CHANG Zhaogang
- WANG Libin
- PEI Xianfeng
- ZHOU Qi
- Research Institute of Coal Chemistry
- China Coal Research Institute Co.
- Ltd.
- State Key Laboratory of Coal Mining and Clean Utilization
- National Energy Technology and Equipment Laboratory of Coal Utilization and Emission Control
- CHANG Zhaogang
- WANG Libin
- PEI Xianfeng
- ZHOU Qi
- Research Institute of Coal Chemistry
- China Coal Research Institute Co.
- Ltd.
- State Key Laboratory of Coal Mining and Clean Utilization
- National Energy Technology and Equipment Laboratory of Coal Utilization and Emission Control