Influence of equivalence ratio of reduction zone on preheating combustion characteristics of pulverized coal
ZHANG Yi;ZHANG Jiahang;ZHU Jianguo;LIU Jingzhang;
Abstract:
Preheating combustion is a new technology of high temperature preheating modification of pulverized coal and re-combustion of preheated fuel. Based on the 30 kW pulverized coal preheating combustion test apparatus, the influence of the change of the equivalence ratio in the reduction zone on the preheating combustion characteristics of the pulverized coal was researched by basically keeping the operating parameters of the circulating fluidized bed equivalence ratio, preheating temperature, and excess air coefficient unchanged. The results show that the main combustion zone of the downward combustion chamber moves toward the top nozzle, the temperature near the nozzle increases, and the temperature along the downward combustion chamber decreases with the increase of the distance from the nozzle when the equivalence ratio of the reduction zone increases. From the nozzle of the downward combustion chamber to the reducing zone where the tertiary air is fed, it is found that the nitrogen-containing gas mainly exists in the form of NO_2. In the oxidizing zone of the downward combustion chamber after the tertiary air being fed, the nitrogen-containing gas mainly exists in the form of NO. The increase of the equivalence ratio of the reduction zone reduces the CO concentration in the reduction zone of the downward combustion chamber, that is, the reducing atmosphere is weakened. The inhibition effect of low concentration of CO content on NO_2 reduction is weakened, resulting in proportion increase of NO_2 reduced to N_2. The NO_2 concentration in the reduction zone is reduced. The ratio of NO_2 being reduced to N_2 increases. The NO concentration in the oxidizing atmosphere also decreases with the increase of the air equivalence ratio in the reduction zone. It indicates that the form of nitrogen-containing gas in the preheated fuel combustion is closely related to the combustion chamber atmosphere. The generated NO and CO concentrations are both low when the reduction zone equivalence ratio is 0.96.
Key Words: preheating combustion;pulverized coal;equivalence ratio of reduction zone;NO_x
Foundation: 国家重点研发计划资助项目(2018YFB0604201)
Authors: ZHANG Yi;ZHANG Jiahang;ZHU Jianguo;LIU Jingzhang;
References:
- [1] IEA.World Energy Outlook 2017[R].Paris:IEA,2017.
- [2] 中华人民共和国国家统计局.中国统计年鉴2019[M].北京:中国统计出版社,2019.
- [3] CHAI J,DU M F,LIANG T,et al.Coal consumption in China:How to bend down the curve?[J].Energy Economics,2019,80:38-47.
- [4] 朱书骏.煤/半焦富氧预热燃烧特性及NOx排放特性试验研究[D].北京:中国科学院大学,2019.
- [5] RIBEIRETE A,COSTA M.Impact of the air staging on the performance of a pulverized coal fired furnace[J].Proceedings of the Combustion Institute,2009,32(2):2667-2673.
- [6] YONMO Sung,CHEOREON Moon,SEONGYONG Eom,et al.Co-al-particle size effects on NO reduction and burnout characteristics with air-staged combustion in a pulverized coal-fired furnace[J].Fuel,2016,182:558-567.
- [7] LI Y,FAN W.Effect of char gasification on NOx formation process in the deep air-staged combustion in a 20 kW down flame furnace[J].Applied Energy,2016,164:258-267.
- [8] WENDT J O L,STERNLING C V,MATOVICH M A.Reduction of sulfur trioxide and nitrogen oxides by secondary fuel injection[J].Symposium(International) on Combustion,1973,14(1):897-904.
- [9] 吕清刚,朱建国,牛天钰,等.煤粉高温预热方法:CN101158468[P].2008-04-09.
- [10] WANG J,ZHU J G,LYU Q G.Experimental study on combustion characteristics and NOx emissions of pulverized anthracite preheated by circulating fluidized bed[J].Journal of Thermal Science,2011,20(4):355-361.
- [11] OUYANG Z,ZHU J G,LU Q G.Experimental study on preheat-ing and combustion characteristics of pulverized anthracite coal[J].Fuel,2013,113:122-127.
- [12] ZHU J G,YAO Y,LU Q G,et al.Experimental investigation of gasification and incineration characteristics of dried sewage sludge in a circulating fluidized bed[J].Fuel,2015,150:441-447.
- [13] LYU Q G,ZHU S J,ZHU J G,et al.Experimental study on NO emissions from pulverized char under MILD combustion in an O2 /CO2 atmosphere preheated by a circulating fluidized bed[J].Fuel Processing Technology,2018,176:43-49.
- [14] YAO Y,ZHU J,LU Q.Experimental study on nitrogen transformation in combustion of pulverized semi-coke preheated in a circulating fluidized bed[J].Energy & Fuels,2015,29(6):3985-3991.
- [15] ZHANG Y,ZHU J,LYU Q,et al.Experimental study on combustion characteristics of pulverized coal based on partial gasification of circulating fluidized bed[J].Energy & Fuels,2020,34(1):989-995.
- [16] ZHANG Y,ZHU J,LYU Q,et al.The ultra-low NOx emission characteristics of pulverized coal combustion after high temperature preheating[J].Fuel,2020,277:118050.
- [17] WANG G,ZHANG J,CHANG W,et al.Structural features and ga-sification reactivity of biomass chars pyrolyzed in different atmospheres at high temperature[J].Energy,2018,147:25-35.
- [18] ZHAO H,LI Y,SONG Q,et al.Investigation on the physicochemical structure and gasification reactivity of nascent pyrolysis and gasification char prepared in the entrained flow reactor[J].Fuel,2019,240:126-137.
- [19] KOU M,ZUO H,NING X,et al.Thermogravimetric study on gasification kinetics of hydropyrolysis char derived from low rank coal[J].Energy,2019,188:116030.
- [20] ZHU X,SHENG C.Influences of carbon structure on the reactivities of lignite char reacting with CO2 and NO[J].Fuel Processing Technology,2010,91(8):837-842.
- [21] WANG G,ZHANG J,CHANG W,et al.Structural features andgasification reactivity of biomass chars pyrolyzed in different atmospheres at high temperature[J].Energy,2018,147:25-35.
- [22] WANG C,WANG P,DU Y,et al.Experimental study on effects of combustion atmosphere and coal char on NO2 reduction under oxy-fuel condition[J].Journal of the Energy Institute,2019,92(4):1023-1033.
- ZHANG Yi
- ZHANG Jiahang
- ZHU Jianguo
- LIU Jingzhang
- Institute of Engineering Thermophysics
- Chinese Academy of Sciences
- University of Chinese Academy of Sciences
- ZHANG Yi
- ZHANG Jiahang
- ZHU Jianguo
- LIU Jingzhang
- Institute of Engineering Thermophysics
- Chinese Academy of Sciences
- University of Chinese Academy of Sciences