FENG Shizhan;LENG Changyu;WANG Luxiang;GONG Xinyi;XU Menjiao;GUO Nannan;AI Lili;ZHANG Qing;

• 1:School of Chemistry
• 2:Xinjiang University

Abstract：

Based on the technology theories of molecular chemical engineering and nanomaterials science, the development and application of coal-based functional carbon materials are of great significance to realize the clean utilization of coal resources, as well as the upgrading of high-value-added coal industries. Coal is the natural materials consisting of aromatic and hydrogenated aromatic groups with a three-dimensional(3D) cross-linked network structure. The unique molecular properties of coal(coal derivatives) provide great potential for the synthesis of a variety of coal-based functional carbon materials. Much progress has been made in coal-based functional carbon materials in the last two decades, which needs to be clarify the current status and development direction of functional carbon materials prepared from coal and its derivatives. The controlled preparation of zero-dimensional to three-dimensional coal-based functional carbon materials has been achieved by using molecular shear, chemical vapor deposition, arc discharge, electrostatic spinning, and other technical means, and the current research status of coal-based graphene carbon quantum dots, carbon spheres, carbon nanotubes, carbon fibers, coal-based graphene and coal-based porous carbon has been systematically sorted out. The advantages and shortcomings of multi-dimensional coal-based functional carbon materials in the fields of energy storage, catalysis, and interfacial separation were summarized. It analyzed and discussed the problems faced by coal-based functional carbon materials such as low controllability, complex molecular structure and the difficulty of synthesis means for large-scale application. This review will provide some reference and insight into the design, preparation, and application of novel coal-based functional carbon materials.

Key Words： coal;coal-based functional carbon materials;design strategies;preparation methods;application areas

Abstract:

Keywords:

Foundation: 新疆维吾尔自治区杰出青年科学基金资助项目(2021D01E09)

Authors: FENG Shizhan;LENG Changyu;WANG Luxiang;GONG Xinyi;XU Menjiao;GUO Nannan;AI Lili;ZHANG Qing;

DOI: 10.13226/j.issn.1006-6772.CA23011113

References：

• [1] 林光平，刘兆川，聂立，等.煤与可再生能源深度耦合的典型零碳综合能源系统构建[J].洁净煤技术，2022,28(11):90-104.LIN Guangping,LIU Zhaochuan,NIE Li,et al.Construction of a typical zero-carbon integrated energy system with deep coupling of coal and renewable energy[J].Clean Coal Technology,2022,28(11):90-104.
• [2] 王晓磊，陈贵锋，李文博，等.双碳背景下煤炭清洁高效利用方向构建[J].煤质技术，2021,36(6):1-5.WANG Xiaolei,CHEN Guifeng,LI Wenbo,et al.Construction of coal clean and efficient utilization direction under the background of double carbon[J].Coal Quality Technology,2021,36(6):1-5.
• [3] 邵敏珠.煤炭资源的现状及利用前景分析[J].科技传播，2013,105(2):85-86.SHAO Minzhu.Analysis of the current situation and utilization prospect of coal resources[J].Science and Technology Communication,2013,105(2):85-86.
• [4] 陈鹏.煤炭利用的新途径-煤制高聚物与高碳材料[J].煤炭科学技术，1995,23(1):41-44.CHEN Peng.A new way of coal utilization-coal polymers and high carbon materials[J].Coal Science and Technology,1995,23(1):41-44.
• [5] LI Hongqiang,HE Xiaojun,WU Tingting,et al.Synthesis,modification strategies and applications of coal-based carbon materials[J].Fuel Processing Technology,2022,230:1-18.
• [6] 张永，杨琪，邵渊，等.煤基功能碳材料的合成及储能应用[J].煤炭学报，2022:1-18.[2022-11-17](2023-01-05)DOI:10.13225/j.cnki.jccs.2022.1215.ZHANG Yong,YANG Qi,SHAO Yuan,et al.Synthesis of coal-based functional carbon materials and energy storage applications[J].Journal of China Coal Society,2022:1-18.[2022-11-17](2023-01-05)DOI:10.13225/j.cnki.jccs.2022.1215.
• [7] 张天开，王琪，张永发.煤基碳纳米管制备技术和生长机理研究进展[J].洁净煤技术，2020,26(1):139-150.ZHANG Tiankai,WANG Qi,ZHANG Yongfa.Progress in the preparation technology and growth mechanism of coal-based carbon nanotubes[J].Clean Coal Technology,2020,26(1):139-150.
• [8] LI Yuda,CHEN Xingqi,ZENG Zihao,et al.Coal-based electrodes for energy storage systems:Development,challenges,and prospects[J].ACS Applied Energy Materials,2022,5(6):7874-7888.
• [9] AKASH S Rasal,SUDESH Yadav,ANCHAL Yadav,et al.Car-bon quantum dots for energy applications:A review[J].ACS Applied Nano Materials,2021,4(7):6515-6541.
• [10] LOU Mengran,WANG Ruiying,ZHANG Jie,et al.Optimized synthesis of nitrogen and phosphorus dual-doped coal-based carbon fiber supported Pd catalyst with enhanced activities for formic acid electrooxidation[J].ACS Applied Materials & Interfaces,2019,11(6):6431-6441.
• [11] TIAN Lin,LI Zhao,WANG Peng,et al.Carbon quantum dots for advanced electrocatalysis[J].Journal of Energy Chemistry,2021,55(6):279-294.
• [12] FENG Shizhan,LUO Wanxia,WANG Luxiang,et al.Prepar-ation and property of extremely stable superhydrophobic carbon fibers with core-shell structure[J].Carbon,2019,150(5):284-291.
• [13] 陈鸿，刘其霞，季涛，等.碳材料在纳米纤维油水分离膜中的应用进展[J].棉纺织技术，2022,50(7):79-84.CHEN Hong,LIU Qixia,JI Tao,et al.Advances in the application of carbon materials in nanofiber oil-water separation membranes[J].Cotton Textile Technology,2022,50(7):79-84.
• [14] CUI Lin,REN Xin,SUN Mengtao,et al.Programming pluripotent precursor cells derived from Xenopus embryos to generate specific tissues and organs[J].Nanomaterials,2010,1(3):413-426.
• [15] SHEN Jianhua,ZHU Yihua,YANG Xiaoling,et al.Graphene quantum dots:Emergent nanolights for bioimaging,sensors,catalysis and photovoltaic devices[J].Chemical Communications,2012,48(31):3686-3699.
• [16] LU Jiong,PEI Shan Emmeline Yeo,CHEE Kwan Gan,et al.Transforming C60 molecules into graphene quantum dots[J].Nature Nanotechnology,2011,6(4):247-252.
• [17] 薄纯辉，姜维佳，王玉高，等.煤基碳量子点合成研究进展[J].应用化学，2021,38(7):767-788.BO Chunhui,JIANG Weijia,WANG Yugao,et al.Advances in the synthesis of coal-based carbon quantum dots[J].Applied Chemistry,2021,38(7):767-788.
• [18] JONATHAN P Mathews,ALAN L Chaffee.The molecular representations of coal:A review[J].Fuel,2012,96(11):1-14.
• [19] XU Ying,WANG Shengnan,HOU Xiaoyan,et al.Coal-derived nitrogen,phosphorus and sulfur co-doped graphene quantum dots:A promising ion fluorescent probe[J].Applied Surface Science,2018,445(3):519-526.
• [20] GENG Bijiang,YANG Dewen,ZHENG Fengfeng,et al.Facile conversion of coal tar to orange fluorescent carbon quantum dots and their composite encapsulated by liposomes for bioimaging[J].New Journal of Chemistry,2017,41(23):14444-14451.
• [21] MONIKANKANA Saikia,JAMES C Hower,TONKESWAR Das,et al.Feasibility study of preparation of carbon quantum dots from Pennsylvania anthracite and Kentucky bituminous coals[J].Fuel,2019,243(1):433-440.
• [22] YE Ruquan,XIANG Changsheng,LIN Jian,et al.Coal as an abundant source of graphene quantum dots[J].Nature Communications,2013,4:1-6.
• [23] HU Chao,YU Chang,LI Mingyu,et al.Chemically tail-oring coal to fluorescent carbon dots with tuned size and their capacity for Cu(II) detection[J].Small,2014,10(23):4926-4933.
• [24] HU Shengliang,WEI Zhijia,CHANG Qing,et al.A facile and gr-een method towards coal-based fluorescent carbon dots with photocatalytic activity[J].Applied Surface Science,2016,378(4):402-407.
• [25] GAN Xuemeng,YUAN Renlu,ZHU Jiayao,et al.Ultra-fine carbon nanosheets from coal oxidation for tri-functional improvement of carbon nanofiber fabrics[J].Carbon,2023,201(9):381-389.
• [26] 朱家瑶.石墨烯量子点改性静电纺丝炭纤维膜的制备及其在水油分离中的应用[D].乌鲁木齐：新疆大学，2018.
• [27] 何一涛.碳纤维基超级电容器电极材料的制备与应用[D].乌鲁木齐：新疆大学，2016.
• [28] LI Zhen,QIN Ping,WANG Liang,et al.Amine-enriched graphene quantum dots for high-pseudocapacitance supercapacitors[J].Electrochimica Acta,2016,208(5):260-266.
• [29] ZHANG Su,ZHU Jiayao,QING Yan,et al.Construction of hierarchical porous carbon nanosheets from template-assisted assem-bly of coal-based graphene quantum dots for high performance supercapacitor electrodes[J].Materials Today Energy,2017,6(8):36-45.
• [30] ZHANG Su,ZHU Jiayao,QING Yan,et al.Ultramicroporous ca-rbons puzzled by graphene quantum dots:Integrated high gravimetric,volumetric,and areal capacitances for supercapacitors[J].Advanced Functional Materials,2018,28(52):1-10.
• [31] QING Yan,JIANG Yuting,LIN He,et al.Boosting the supercapacitor performance of activated carbon by constructing overall conductive networks using graphene quantum dots[J].Journal of Materials Chemistry A,2019,7(11):6021-6027.
• [32] ZHANG Yating,ZHANG Kaibo,JIA Kaili,et al.Preparation of coal-based graphene quantum dots/α-Fe2O3 nanocomposites and their lithium-ion storage properties[J].Fuel,2019,241(12):646-652.
• [33] 谭一飞.碳球的研究与应用进展[J].广东化工，2017,44(356):98-100.TAN Yifei.Progress of research and application of carbon spheres[J].Guangdong Chemical Industry,2017,44(356):98-100.
• [34] 彭亮，彭华容，李伟.功能介孔碳纳米球的合成与应用研究进展[J].黑龙江大学自然科学学报，2021,38(4):433-444.PENG Liang,PENG Huarong,LI Wei.Progress in the synthesis and application of functional mesoporous carbon nanospheres[J].Journal of Natural Sciences,Heilongjiang University,2021,38(4):433-444.
• [35] 王苗苗，赵静，张建安，等.纳米多孔炭球的制备及应用进展[J].炭素技术，2018,37(1):1-5.WANG Miaomiao,ZHAO Jing,ZHANG Jian′an,et al.Progress in the preparation and application of nanoporous carbon spheres[J].Carbon Technology,2018,37(1):1-5.
• [36] 吴为亚，程江来，商永嘉.多孔碳球制备及应用研究进展[J].化工新型材料，2014,42(12):217-219.WU Weiya,CHENG Jianglai,SHENG Yongjia.Research progress on the preparation and application of porous carbon spheres[J].New Chemical Materials,2014,42(12):217-219.
• [37] TIAN Hao,LIANG Ji,LIU Jian.Nanoengineering carbon spheres as nanoreactors for sustainable energy applications[J].Advanced Materials,2019,31(50):1903886-1903916.
• [38] QIU Jieshan,LI Yongfeng,WANG Yunpeng,et al.A novel form of carbon micro-balls from coal[J].Carbon,2003,41(4):767-772.
• [39] LUO Shiyuan,LI Jingze,ZHANG Xialan,et al.Preparation of mo-nodispersed hollow carbon spheres by direct pyrolysis of coal-tar pitch in the presence of aluminum isopropoxide[J].Journal of Analytical and Applied Pyrolysis,2018,135:10-14.
• [40] SUN Shuai,WANG Lei,WANG Chengyang,et al.Vacuum-assisted synthesis of spherical activated carbon using coal tar pitch with low softening point by copolymeri-zation[J].Vacuum,2018,158(10):215-217.
• [41] GUO Mingxi,GUO Jixi,TONG Fenglian,et al.Hierarchical po-rous carbon spheres constructed from coal as electrode materials for high performance supercapacitors[J].RSC Advances,2017,7(72):45363-45368.
• [42] LYU Yan,CHEN Jingjing,JIA Wei,et al.N/S co-doped coal-based porous carbon spheres as electrode materials for high performance supercapacitors[J].RSC Advances,2020,10(19):11033-11038.
• [43] 陈景景.杂原子掺杂煤基多孔炭球的制备及其电容性能研究[D].乌鲁木齐：新疆大学，2019.
• [44] SUMIO Iijima,TOSHINARI Ichihashi.Single-shell carbon nanotubes of 1-nm diameter[J].Nature,1993,364(19):603-605.
• [45] DAI Hongjie.Carbon nanotubes opportunities and challenges[J].Surface Science,2002,500(1):218-241.
• [46] YAN Li.Carbon nanotube research in Its 30th Year[J].ACS Nano,2021,15(6):9197-9200.
• [47] 潘苏寅.碳纳米管的制备方法[J].科技开发，2020(16):150-151.PAN Suyin.Preparation method of carbon nanotubes[J].Science and Technology Development,2020(16):150-151.
• [48] 郑明东，何孝军，伊廷锋，等.不同压力下碳纳米管的电弧法合成及其表征[J].功能材料与器件学报，2009,15(2):159-164.ZHENG Mingdong,HE Xiaojun,YI Tingfeng,et al.Synthesis and characterization of carbon nanotubes by electric arc method under different pressures[J].Journal of Functional Materials and Devices,2009,15(2):159-164.
• [49] JIA Xilai,WEI Fei.Advances in production and applications of carbon nanotubes[J].Topics in Current Chemistry,2017,375(1):1-35.
• [50] ZHANG Shuchen,ZHANG Na,ZHANG Jin.Controlled synt-hesis of carbon nanotubes:Past,present and future[J].Acta Physico-Chimica Sinica,2020,36(1):1-16.
• [51] WILSON M A,PATNEY H K,KALMAN J.New developments in the formation of nanotubes from coal[J].Fuel,2002,81(1):5-14.
• [52] 吴霞，王鲁香，刘浪，等.新疆煤基碳纳米管的调控制备[J].无机化学学报，2013,29(9):1842-1848.WU Xia,WANG Luxiang,LIU Lang,et al.Regulated preparation of coal-based carbon nanotubes in Xinjiang[J].Journal of Inorganic Chemistry,2013,29(9):1842-1848.
• [53] 邱介山，张凡，周颖，等.煤基纳米碳管的制备研究[C]//2000年国外材料科学与工程发展动向研讨会.大连：中国材料研究学会，2000.
• [54] LI Jun,CAO Yali,WANG Luxiang,et al.Cost-effective synthesis of bamboo-structure carbon nanotubes from coal for reversible lithium storage[J].RSC Advances,2017,7(55):34770-34775.
• [55] LIU Huimin,HUANG Xinning,LU Zhenjie,et al.Trace metals dramatically boost oxygen electrocatalysis of N-doped coal-derived carbon for zinc-air batteries[J].Nanoscale,2020,12(17):9628-9639.
• [56] LU Zhenjie,YAO Songdong,DONG Yanzeng,et al.Earth-abundant coal-derived carbon nanotube/carbon composites as efficient bifunctional oxygen electrocatalysts for rechargeable zinc-air batteries[J].Journal of Energy Chemistry,2021,56(7):87-97.
• [57] 吴长清.煤基掺氮碳纳米管负载铂基催化剂及其电催化性能研究[D].西安：西安科技大学，2021.
• [58] 从少领，赵捷，杨玉飞，等.煤基聚苯胺制掺N 碳微纳米管的实验研究[J].化工学报，2021,72(9):4950-4960.CONG Shaoling,ZHAO Jie,YANG Yufei,et al.Experimental study of N-doped carbon micro-nanotubes from coal-based polyaniline[J].Journal of Chemical Engineering,2021,72(9):4950-4960.
• [59] BRADLEY A Newcomb.Processing,structure,and properties of carbon fibers[J].Composites Part A:Applied Science and Manufacturing,2016,91(10):262-282.
• [60] 胡世棋，张天昊，刘其霞，等.聚丙烯腈基活性碳纤维制备及应用研究进展[J].纺织科学与工程学报，2022,39(4):92-97.HU Shiqi,ZHANG Tianhao,LIU Qixia,et al.Research progress on the preparation and application of polyacrylonitrile-based activated carbon fibers[J].Journal of Textile Science and Engineering,2022,39(4):92-97.
• [61] 谭媛，韩香，齐肖阳.碳纤维材料的应用研究进展[J].山东化工，2021,50(13):46-47.TAN Yuan,HAN Xiang,QI Xiaoyang.Research progress on the application of carbon fiber materials[J].Shandong Chemical Industry,2021,50(13):46-47.
• [62] EIICHI Yasuda.Carbon fiber from micro to nano[J].Carbon,2011,49(14):4953-4955.
• [63] HUO Yan,XIU Shijian,MENG Longyue,et al.Solvothermal synthesis and applications of micro/nano carbons:A review[J].Chemical Engineering Journal,2023,451(2):1-24.
• [64] 邹科，龙云泽，吴佑实.静电纺丝制备纳米纤维的进展及应用[J].合成纤维工艺，2007,30(3):54-57.ZOU Ke,LONG Yunze,WU Youshi.Progress and applications of electrostatic spinning for the preparation of nanofibers[J].Synthetic Fiber Technology,2007,30(3):54-57.
• [65] ZHAO Hongyang,WANG Luxiang,JIA Dianzeng,et al.Coal based activated carbon nanofibers prepared by electrospinning[J].Journal of Materials Chemistry A,2014,2(24):9338-9344.
• [66] 赵洪洋.煤基碳纳米纤维的制备及其在超级电容器中的应用[D].乌鲁木齐：新疆大学，2014.
• [67] LIU Xuguang,JI Weiyun,ZHANG Yan,et al.The morphology and electrical resistance of long oriented vapor-grown carbon fibers synthesized from coal pitch[J].Carbon,2008,46(1):154-158.
• [68] YANG Jianxiao,KOJI Nakabayashi,JIN Miyawaki,et al.Preparation of pitch based carbon fibers using hyper-coal as a raw material[J].Carbon,2016,106(5):28-36.
• [69] WANG Tongtong,HE Xin,GONG Weibo,et al.Flexible carbon nanofibers for high-performance free-standing supercapacitor electrodes derived from powder river basin coal[J].Fuel,2020,278:1-9.
• [70] SONG Xianli,GUO Jixi,GUO Mingxi,et al.Freestanding needle-like polyaniline-coal based carbon nanofibers composites for flexible supercapacitor[J].Electrochimica Acta,2016,206(4):337-345.
• [71] HE Yitao,WANG Luxiang,JIA Dianzeng.Coal/PAN interconnected carbon nanofibers with excellent energy storage performance and electrical conductivity[J].Electrochimica Acta,2016,194(1):239-245.
• [72] ZHAO Xiaojuan,JIA Wei,WU Xueyan,et al.Ultrafine MoO3 anchored in coal-based carbon nanofibers as anode for advanced lithium-ion batteries[J].Carbon,2020,156(9):445-452.
• [73] 程仲富，赵小娟，范伟东，等.煤基炭纳米纤维作为锂离子电池负极的研究[J].炭素技术，2021,40(3):20-25.CHENG Zhongfu,ZHAO Xiaojuan,FAN Weidong,et al.Study of coal-based carbon nanofibers as anode for lithium-ion batteries[J].Carbon Technology,2021,40(3):20-25.
• [74] GAO Junting,WANG Xingchao,LU Xiaoquan,et al.Coal-based hierarchically porous carbon nanofibers as high-performance anode for sodium-ion batteries[J].Chem-ElectroChem,2022,9(15):1-9.
• [75] GONG Xinyi,ZHANG Su,LUO Wanxia,et al.Enabling a large accessible surface area of a pore-designed hydrophilic carbon nanofiber fabric for ultrahigh capacitive deionization[J].ACS Applied Materials & Interfaces,2020,12(44):49586-49595.
• [76] 崔曦.煤基超亲水材料的制备及其在油水分离中的应用[D].乌鲁木齐：新疆大学，2021.
• [77] WANG Yu,LI Sis,YANG Haiyana,et al.Progress in the functional modification of graphene/graphene oxide:A review[J].RSC Advances,2020,10(26):15328-15345.
• [78] REN Shuai,RONG Ping,YU Qi.Preparations,properties and applications of graphene in functional devices:A concise review[J].Ceramics International,2018,44(11):11940-11955.
• [79] DAS Bappaditya,KUNDU Rajen,CHAKRAVARTY Sanchita.Preparation and characterization of graphene oxide from coal[J].Materials Chemistry and Physics,2022,290:1-6.
• [80] 李君，李井峰，赵阳，等.煤基石墨烯制备工艺研究进展[J].洁净煤技术，2021,27(S2):206-211.LI Jun,LI Jingfeng,ZHAO Yang,et al.Research progress of coal-based graphene preparation process[J].Coal Clean Technology,2021,27(S2):206-211.
• [81] ZHOU Quan,ZHAO Zongbin,ZHANG Yating,et al.Graphene sheets from graphitized anthracite coal:Preparation,decoration,and application[J].Energy & Fuels,2012,26(8):5186-5192.
• [82] GERARDINE G Botte,SANTOSH H Vijapur,WANG Dan,et al.An investigation of growth mechanism of coal derived graphene films[J].Materials Today Communications,2017,11(4):147-155.
• [83] LYU You,XING Baolin,ZHENG Mingkun,et al.Hydrothermal synthesis of ultra-Light coal-based graphene oxide aerogel for efficient removal of dyes from aqueous solutions[J].Nanomaterials 2018,8(9):1-17.
• [84] DAS Tonkeswar,HIMANI Chauhan,SASANKA Deka,et al.Promising carbon nanosheet-based supercapacitor electrode materials from low-grade coals[J].Microporous and Mesoporous Materials,2017,253(6):80-90.
• [85] XU Hao,LIN Qilang,ZHOU Tianhong,et al.Facile preparation of graphene nanosheets by pyrolysis of coal-tar pitch with the presence of aluminum[J].Journal of Analytical and Applied Pyrolysis,2014,110(10):481-485.
• [86] SUN Lulu,ZHAO Zongbin,SUN Yang,et al.Activated coal-based graphene with hierarchical porous structures for ultra-high energy density supercapacitors[J].Diamond and Related Materials,2020,106:1-8.
• [87] GAO Feng,QU Jiangying,ZHAO Zongbin,et al.A green strat-egy for the synthesis of graphene supported Mn3O4 nanocomposit-es from graphitized coal and their supercapacitor application[J].Carbon,2014,80(9):640-650.
• [88] XING Baolin,ZENG Huihui,Huang Guangxu,et al.Porous graphene prepared from anthracite as high performance anode materials for lithium-ion battery applications[J].Journal of Alloys and Compounds,2019,779(11):202-211.
• [89] ZHONG Min,YAN Jiawei,WU Haixia,et al.Multilayer graph-ene spheres generated from anthracite and semi-coke as anode materials for lithium-ion batteries[J].Fuel Processing Technology,2020,198:1-8.
• [90] WANG Jian,CUI Yongli,GU Yue,et al.Coal-based modified carbon for high performance sodium-ion battery[J].Solid State Ionics,2021,368:1-8.
• [91] 王秀，郝健，郭庆杰.多孔碳结构调控及其在二氧化碳吸附领域的应用[J].洁净煤技术，2021,27(1):135-143.WANG Xiu,HAO Jian,GUO Qingjie.Structural modulation of porous carbon and its application in carbon dioxide adsorption[J].Clean Coal Technology,2021,27(1):135-143.
• [92] BORCHARDT Lars,ZHU Qilong,CASCO Mirian E,et al.Toward a molecular design of porous carbon materials[J].Materials Today,2017,20(10):592-610.
• [93] DONG Duo,ZHANG Yongsheng,XIAO Yi,et al.Oxygen-enriched coal-based porous carbon under plasma-assisted MgCO3 activation as supercapacitor electrodes[J].Fuel,2022,309:1-10.
• [94] HE Xiaojun,MA Hao,WANG Jingxian,et al.Porous carbon nanosheets from coal tar for high-performance supercapacitors[J].Journal of Power Sources,2017,357(4):41-46.
• [95] WANG Qian,YAN Jun,WEI Tong,et al.Two-dimensional mesoporous carbon sheet-like framework material for high-rate supercapacitors[J].Carbon,2013,60(4):481-487.
• [96] WEI Qinhong,QIN Fangfang,MA Qingxiang,et al.Coal tar-and-residual oil-derived porous carbon as metal-free catalyst for nitroarene reduction to aminoarene[J].Carbon,2019,141(9):542-552.
• [97] WANG Luxiang,WANG Rongrong,ZHAO Hongyang,et al.High rate performance porous carbon prepared from coal for supercapacitors[J].Materials Letters,2015,149(11):85-88.
• [98] ZOU Yile,WANG Hongfang,XU Lianfei,et al.Synergistic effect of CO2 and H2O co-activation of Zhundong coal at a low burn-off rate on high performance supercapacitor[J].Journal of Power Sources,2023,556:1-12.
• [99] GAO Shasha,TANG Yakun,WANG Lei,et al.Coal-based hierarchical porous carbon synthesized with a soluble salt self-assembly-assisted method for high performance supercapacitors and Li-ion batteries[J].ACS Sustainable Chemistry & Engineering,2018,6(3):3255-3263.
• [100] XING Baolin,ZHANG Chuantao,CAO Yijun,et al.Prepar-ation of synthetic graphite from bituminous coal as anode materials for high performance lithium-ion batteries [J].Fuel Processing Technology,2018,172(12):162-171.
• [101] HAN Liang,ZHU Xiao,YANG Fei,et al.Eco-conversion of coal into a nonporous graphite for high-performance anodes of lithium-ion batteries[J].Powder Technology,2021,382(12):40-47.
• [102] XIAO Nan,ZHANG Xiaoyu,LIU Chang,et al.Coal-bas-ed carbon anodes for high-performance potassium-ion batteries[J].Carbon,2019,147(1):574-581.
• [103] CHEN Jinfeng,FENG Jianmin,DONG Lei,et al.Nanoporous coal via Ni-catalytic graphitization as anode materials for potassium ion battery[J].Journal of Electro-analytical Chemistry,2020,862(1):1-9.
• [104] ZHUANG Zhiheng,CUI Yongli,ZHU Honggang,et al.Coal-based amorphous carbon as economical anode material for sodium-ion battery[J].Journal of the Electro-chemical Society,2018,165(10):A2225-A2232.
• [105] 胡晓琴.煤基碳纤维负载二硫化钼复合材料的合成及电催化析氢性能研究[D].乌鲁木齐：新疆大学，2021.
• [106] 宋营营.煤基碳材料的设计、制备及其电容去离性能研究[D].乌鲁木齐：新疆大学，2021.
• [107] ANNA Marzec.Towards an understanding of the coal structure:A review[J].Fuel Processing Technology,2002,77(78):25-32.