XIA Liquan;CHEN Guifeng;LI Wenbo;GAO Minglong;

• 1:China Coal Research Institute
• 2:Coal Chemical Branch of China Coal Research Institute
• 3:Energy State Key Laboratory of Coal Efficient Utilization and Energy saving Emission Reduction
• 4:Beijing Key Laboratory of Coal Based Carbon Materials

Abstract：

Coking,as a traditional coal chemical industry,has developed rapidly,and most of coking enterprises are distributed in North China where there is relatively little water.Therefore,the effective treatment of coking wastewater plays an important role in the sustainable and stable development of coking industry. In this paper,the research progress of coking wastewater treatment technology was discussed based on the source and water quality characteristics of coking wastewater. The shortcomings of the current coking wastewater treatment technology were pointed out,and its development direction was prospected. Coking wastewater is a typical industrial wastewater,which is difficult to be treated because of its characteristics such as large amount of production and high concentration of organic pollutants.Domestic coking enterprises have relatively weak understanding about the importance of pretreatment section,at present the traditional pretreatment technology is still dominant,and the problems such aslow efficiency,high energy consumption and secondary pollution are outstanding,but the magnetic separation technique in the pretreatment section can be of further application.The anaerobic,anoxic and aerobic technology developed in the 20 th century are mainly used in the biochemical treatment section,which are mature and have been widely used.But the biochemical treatment technology has higher requirements for water quality,especially the wastewater carbon nitrogen ratio( C/N)and the concentration of organic carbon source determine to the final effect of biochemical treatment.Microorganis technology and the development of membrane bioreactor in the future will have great development and breakthrough,and anaerobic technology because of its high energy utilization has attracted the attention of many scholars,and the application of anaerobic technology is helpful to build the ideal type of modern wastewater treatment plants.Deep processing section mainly solves the problem of biochemical effluent substandard,and in the " zero emissions" process,there are higher requirements for the water quality of the membrane,so the depth of processing section is to degradate some organic matters more precisely and specifically,and advanced oxidation technology as a new processing technology is developing rapidly and is gradually adopted by more coking enterprises.The results show that the synergetic effect of the optimization coupling of several treatment technologies can further enhance the treatment effect and make the coking wastewater meet the discharge or reuse standards.With the increasingly strict environmental protection policy,factors such as the popularization of " zero discharge" of wastewater,the acceptable treatment cost of enterprises and the water quality characteristics of coking wastewater jointly determine that the coupling and combination of relatively mature deep treatment technologies such as advanced oxidation technology and membrane separation technology will be the key direction of future development.The development trend of coking wastewater treatment in the future is to improve the utilization rate of resources,improve treatment capacity and efficiency,and reduce energy consumption and operating cost. In the process of coking waste water treatment,membrane separation technology is widely used and at the same time,it can produce high concentrations of saline wastewater.The effective treatment of saline wastewater is related to the points and the purity of salt products,and if the organic pollutants in concentrated brine can not be effectively treated,the treatment cost of the follow-up section will be increased and even the hazardous waste of environmental pollution will be produced.Therefore,the effective treatment for high concentration brine is also the focus of the research community urgent problem.

Key Words： coking wastewater;pretreatment;biochemical treatment;deep processing;technology coupling

Abstract:

Keywords:

Foundation: 中国煤炭科工集团有限公司科技创新创业资金专项资助项目(2018MS002)

Authors: XIA Liquan;CHEN Guifeng;LI Wenbo;GAO Minglong;

DOI: 10.13226/j.issn.1006-6772.19060301

References：

• [1] ZHU Hao,HAN Hongjun.Overview of the state of the art of processes and technical bottlenecks for coal gasification wastewater treatment[J]. Science of the Total Environment,2018,637:1108-1126.
• [2] XIONG Rihua,WEI Chang.Current status and technology trends of zero liquid discharge at coal chemical industry in China[J].Journal of Water Process Engineering,2017(19):346-351.
• [3] LIU Jinwei,CHENG Shihan,CAO Na,et al. Actinia-like multifunctional nanocoagulant for single-step removal of water contaminants[J].Nature Nanotechnology,2019,14(2):191-191.
• [4] VLAD M,CHIRIAC A,CONSTANTINESCU S,et al. Removal of the pollutants from wastewater through coagulation-flocculation process[J].Journal of Environmental Protection&Ecology,2011,12(3A):1517-1524.
• [5]唐纲，杨平，王吉白，等．超导磁分离过程的混絮凝影响因素[J]．环境科学与技术，2018,41(7):60-64.TANG gang,YANG Ping,WANG Jibai,et al. Factors influencing flocculation in superconducting magnetic separation process[J].Environmental Science and Technology,2008,41(7):60-64.
• [6]钱宇，杨思宇，马东辉，等．煤气化高浓酚氨废水处理技术研究进展[J]．化工进展，2016,35(6):1884-1893.QIAN Yu,YANG Siyu,MA Donghui,et al. Research progress of coal gasification high concentration phenolic ammonia wastewater treatment technology[J]. Progress of Ohemical Industry,2016,35(6):1884-1893.
• [7]张宁．有机改性膨润土和介孔碳的制备及其对废水中酚类物质吸附性能和吸附机理的研究[D]．太原:太原理工大学，2018.ZHANG Ning. Preparation of organically modified bentonite and mesoporous carbon and their adsorption properties and mechanism for phenols in wastewater[D].Taiyuan:Taiyuan University of Technology,2018.
• [8] CHEN Yun,WANG Zhuo,LI Libo.Liquid-liquid equilibria for ternary systems:Methyl butyl ketone+phenol+water and methyl butyl ketone+hydroquinone+water at 298[J]. Journal of Chemical&Engineering Data,2014,59(9):2750-2755.
• [9]陈贵锋，高明龙．MK型络合萃取剂萃取脱酚实验研究[J]．煤化工，2018,46(2):54-57.CHEN Guifeng,GAO Minglong. Experimental study on extraction and dephenolization of MK complexing extractor[J]. Coal Chemical Industry,2008,46(2):54-57.
• [10] QIN Mohan,LIU Ying,LUO Shuai,et al.Integrated experimental and modeling evaluation of energy consumption for ammonia recovery in bioelectrochemical systems[J]. Chemical Engineering Journal,2017,327:924-931.
• [11]吴限．煤化工废水处理技术面临的问题与技术优化研究[D]．哈尔滨:哈尔滨工业大学，2016.WU Xian.Problems andtechnological optimization of coal chemical wastewater treatment technology[D]. Harbin:Harbin University of Technology,2016.
• [12] DELFORNO Tiago P.Comparative metatranscriptomic analysis of anaerobic digesters treating anionic surfactant contaminated wastewater[J].Science of the Total Environment,2018,6(49):482-494.
• [13]孙国鹏．零价铁—厌氧生物耦合法处理印染废水作用及调控机理研究[D]．济南:山东大学，2011.SUN Guopeng. Study on the effect and regulation mechanism of zero-valent iron-anaerobic biological coupling process for treatment of printing and dyeing wastewater[D].Jinan:Shandong University,2011.
• [14] YANG Bo,WANG Qing,YE Jinshao,et al.Performance and microbial protein expression during anaerobic treatment of alkalidecrement wastewater using a strengthened circulation anaerobic reactor[J].Bioresource Technology,2019,273:40-48.
• [15] REN Y,FERRAZF M,YUAN Q. Biological leachate treatment using anaerobic/aerobic process:Suspended growth-activated sludge versus aerobic granular sludge[J].International Journal of Environmental Science and Technology,2018,15(11):2295-2302.
• [16] CAPODICI M,COSENZA A,TRAPANI D D,et al.Treatment of oily wastewater with membrane bioreactor systems[J]Water,2017,9(6):412-420.
• [17] XU Peng,MA Wencheng. A novel integration of microwave catalytic oxidation and MBBR process and its application in advanced treatment of biologically pretreated Lurgi coal gasification wastewater[J]. Separation and Purification Technology,2018,177:233-238.
• [18] VAZQUEZ I,MARANON E.Treatment of coke wastewater in a sequential batch reactor(SBR)at pilot plant scale[J]. Bioresource Technology,2008,99(10):4192-4198.
• [19] BAI Yaohui,WEN Donghui,ZHAO Cuiet al. Bioaugmentation treatment for coking wastewater containing pyridine and quinoline in a sequencing batch reactor[J]. Applied Microbology and Biotechnology,2010,87(5):1943-1951.
• [20] DU Rui,CAO Shenbin,PENG Yongzhen,et al.Combined partial denitrification(PD)-anammox:A method for high nitrate wastewater treatment[J]. Environment Interanational. 2019,126:707-716.
• [21] ZIMMERMAN J R,LUTHY R G,GHOSH U,et al. Addition of carbon sorbents to reduce PCB and PAH bioavailability in marine sediments:Physicochemical tests[J]. Environmental Science&Technology,2004,38(20):5458-5464.
• [22]刘雪琴．基于高效复合降解菌系的生物活性炭技术深度处理焦化废水的研究[D]．武汉:武汉科技大学，2013.LIU Xueqin.Advancedtreatment of coking wastewater by biological activated carbon technology based on high efficiency compound degrading bacteria[D].Wuhan:Wuhan University of Science and Technology,2013.
• [23] SUN W L,QU Y Z,YU Q,et al.Adsorption of organic pollutants from coking and papermaking wastewaters by bottom ash[J].Journal of Hazardous Materials,2008,154(1/2/3):595-601.
• [24] DUEHOLM M S,MARQUES I G,KARST S M,et al.Survival and activity of individual bioaugmentation strains[J]. Bioresource Technology,2015,186:192-199.
• [25] HERRERO M,STUCKEY D C.Bioaugmentation and its application in wastewater treatment:A review[J]. Chemosphere,2015,140:119-128.
• [26]周成金．生物倍增工艺处理低碳氮比城市污水脱氮效能的研究[D]．哈尔滨:哈尔滨工业大学，2016.ZHOU Chengjin.Study on denitrification efficiency of low carbon nitrogen ratio urban sewage treated by biological multiplication process[D].Harbin:Harbin Institute of Technology,2016.
• [27] FENTON H.Xidation of tartaric acid in the presence of iron[J].Journal of the Chemical Society,Transactions,1894,65:899-910.
• [28] TYAGI M,RANA A,KUMARI S,et al.Adsorptive removal of cyanide from coke oven wastewater onto zero-valent iron:Optimization through response surface methodology,isotherm and kinetic studies[J]. Jouanal of Cleaner Production,2018,20(178):398-407.
• [29] GUCLU D,SIRIN N,SAHINKAYA S,et al.Advanced treatment of coking wastewater by conventional and modified fenton processes[J]. Environmental Process&Sustainable Energy,2013,32(2):176-180.
• [30] HASSAN H B,HAMEED H.Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4[J].Chemical Engineering Journal,2011,171(3):912-918.
• [31] HORIKOSHI Satoshi. Microwave-driven in-liquid plasma in chemical and environmental applications. III:Examination of optimum microwave pulse conditions for prolongation of electrode lifetime,and application to dye-contaminated wastewater[J]. Plasma Chemistry and Plasma Processing,2019,39:1,51-62.
• [32] HUANG Haiming.Highlyefficient recovery of ammonium nitrogen from coking wastewater by coupling struvite precipitation and microwave radiation technology[J]. ACS Sustainable Chemistry&Engineering,2016,4(7):3688-3696.
• [33]曲晓萍．活性炭-微波辐射深度处理焦化废水[J]．华中科技大学学报(城市科学版)，2005,22(4):83-85.QU Xiaoping. Activated carbon-microwave radiation advanced treatment of coking wastewater[J]. Journal of Huazhong University of Science and Technology(Urban Science Edition),2005,22(4):83-85.
• [34] WU Yongmei,ZHANG Jinlong,ZHANG Jinlong,et al.Gel-hydrothermal synthesis of carbon and boron co-doped Ti O2and evaluating its photocatalytic activity[J].Journal of Hazardous Materials,2011,192(1):368-374.
• [35] GAO Min Jiang,WANG Xi Dong.Contrast on COD photo-degradation in coking wastewater catalyzed by Ti O2and Ti O2-Ti O2nanorod arrays[J].Catalysis Today,2011,174(1):79-87.
• [36] ZhANG Mo,ZHU Yongfa.Separation free C3N4-SiO2hybrid hydrogels as high active photocatalysts for TOC removal[J].Applied Catalysis B:Envieonmental,2016,194:105-110.
• [37] KUMAR A,SENGUPTA B,KANNAUJIYA M C,et al.Treatment of coke oven wastewater using ozone with hydrogen peroxide and activated carbon[J]. Desalination and Water Treatment,2017,69:352-365.
• [38] ZHU Xiuping,NI Jinren,LAI Peng,et al.Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using boron-doped diamond electrodes[J]. Water Research,2009,43(17):4347-4355.
• [39] HE X,CHAI Z,LI F,et al. Advanced treatment of biologically pretreated coking wastewater by electrochemical oxidation using Ti/RuO2-Ir O2electrodes[J]. Journal of Chemical Technology&Biotechnology,2013,88(8):1568-1575.
• [40] MA X,WANG R,GUO W,et al.Electrochemical removal of ammonia in coking wastewater using Ti/SnO2+Sb/PbO2anode[J].International Journal of Electrochemical Science,2012,7(7):6012-6024.
• [41] ZHANG Chunhui,ZHANG Wenwen.Advanced treatment of biologically pretreated coking wastewater by a bipolar three-dimensional electrode reactor[J].Envieonmental Technology,2013,34(16):2371-2376.
• [42] ZHANG C,LIN H,CHEN J,et al.Advanced treatment of biologically pre treated coking wastewater by a bipolar threedimensional electrode reactor[J]. Environmental Technology,2013,34(16):2371-2376.
• [43]廖玮，朱廷风，廖传华，等．超临界水氧化技术在能量转化中的应用[J]．水处理技术，2019,45(3):14-17.LIAO Wei,ZHU Tingfeng,LIAO Chuanhua,et al. Application of supercritical water oxidation technology in energy conversion[J].Water Treatment Technology,2019,45(3):14-17.
• [44]夏前勇，郭卫民，申哲民，等．化工废水的超临界水氧化研究[J]．安全与环境工程，2019,28(2):83-93.XIA Qianyong,GUO Weimin,SHEN Zhemin,et al. Supercritical water oxidation of chemical wastewater[J]. Safety and Environmental Engineering,2019,28(2):83-93.
• [45]王立东．焦化废水深度处理与回用研究[D]．上海:华东理工大学，2017.WANG Lidong.Research on advanced treatment and reuse of coking wastewater[D].Shanghai:East China University of Technology,2017.
• [46] HE Zeming,LU Zhiyang,GU Qilinet al.Ceramic-based membranes for water and wastewater treatment[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2019,578:1-20.
• [47]马可可，周律，辛怡颖，等．低温等离子体技术用于废水处理的研究进展[J]．应用化工，2019,48(1):145-150.MA Keke,ZHOU Lyu,XIN yiying,et al. Research progress of low-temperature plasma technology for wastewater treatment[J].Applied Chemical Industry,2019,48(1):145-150.
• [48]段丽娟．沿面放电等离子体降解焦化废水及提高其可生化性的研究[D]．大连:大连理工大学，2013.DUAN Lijuan. Degradation of coking wastewater by surface discharge plasma and improvement of its biodegradability[D].Dalian Dalian University of Technology,2013.
• [49] CHELLA Santhosh,VENUGOPAL Velmurugan,GEROGE Jacob,et al.Role of nonematerials in water treatment applications:A review[J].Chemical Engineering Journal,2016,306:1116-1137.
• [50] PAL Parimal,KUMAR Ramesh. Treatment of coke wastewater:A critical review for developing sustainable management strategies[J].Separtion and Purification Reviews,2014,43(2):89-123.