丁宁,陈千惠,刘丹禾,齐文义
DING Ning,CHEN Qianhui,LIU Danhe,QI Wenyi

• 1:中石化炼化工程(集团)股份有限公司洛阳技术研发中心

摘要(Abstract)：

氢气不仅是一种重要的工业资源，也是“零碳社会”下重要的清洁能源，氢能技术在交通、能源、冶金和化工等领域拥有广阔的应用前景。不过，生产成本、储运技术、安全问题等也长期制约着氢能，尤其是绿氢的应用发展。应明确的是，无论高压储运、氢液化等物理储运方式，或基于“Power to X”策略的化学储氢方式，均难以避免高额的全周期能耗。在理解过程能效，考虑不同储运方式下氢能全生命周期成本的基础上，对比各类技术经济性。其中，液氢和液氨的燃料利用途径在不同时期下均具有良好的经济性，更适宜用作氢能大规模供热供电场下的储运技术。基于此，对制、储氢技术及成本期望进行了归纳，并讨论了氢(氨)能源在大规模发电领域应用的技术经济问题，借鉴不同国家地区氢能发展思路，以期对我国氢能储运技术发展提供参考。
Hydrogen, which has been seen as a kind of significant industrial source, has been increasingly focused as the clean energy in a net-zero carbon emission future, with broad application prospects in the fields of transportation, energy supply, metallurgy and chemical industry. Nevertheless, the development and application of hydrogen, especially green hydrogen, have been restricted with technologies and costs in its production, storage and transport process. It should be confirmed that quite a bit of the energy will be lost in the transformation and transportation process whether in high-pressure compressed form, liquid form or other Power-to-X strategies. Furthermore, it was easy to understand more reliable life cycle economic analysis of hydrogen would be estimated while energy efficiency was considered. By comparison, liquid hydrogen and ammonia were regard as the better methods for large-scale power or heat supply under different periods. Herein, based on the consideration of the energy efficiency of hydrogen, technologies and costs of its production, storage and transport were summarized in this work, together with the large-scale power supply by green hydrogen and ammonia. Comprehending the worldwide green hydrogen outlook would make benefits for China′s transition towards a future where hydrogen will be a major energy player.

关键词(KeyWords)： 氢能;储运技术;经济性;能效;液氢;甲醇;氨
hydrogen energy;storage and transport technology;economy;energy efficiency;liquid hydrogen;methanol;ammonia

Abstract:

Keywords:

基金项目(Foundation): 中石化科技开发资助项目(123021)

作者(Author): 丁宁,陈千惠,刘丹禾,齐文义
DING Ning,CHEN Qianhui,LIU Danhe,QI Wenyi

DOI: 10.13226/j.issn.1006-6772.CN23092001

参考文献(References)：

• [1] 周红军，周颖，徐春明.中国碳中和目标下CO2转化的思考与实践[J].化工进展，2022,41(6):3381-3385.ZHOU Hongjun,ZHOU Ying,XU Chunming.Exploration of the CO2 conversion under China′s carbon neutrality goal[J].Chemical Industrial and Engineering Progress,2022,41(6):3381-3385.
• [2] 徐连兵.我国氢能源利用前景与发展战略研究[J].洁净煤技术，2022,28(9):1-10.XU Lianbing.Research on the prospect and development stategy of hydrogen energy in China[J].Clean Coal Technology,2022,28(9):1-10.
• [3] THOMAS J M,EDWARDS P P,DOBSON P J,et al.Decarbonising energy:The developing international activity in hydrogen technologies and fuel cells[J].Journal of Energy Chemistry,2020,51:405-415.
• [4] MASTROPASQUA L,PEGORIN A,CAMPANARI S.Low fuel utilisation solid oxide fuel cell system for CO2-free hydrogen production in oil refineries[J].Journal of Power Sources,2020,448:227461.
• [5] VALERA-MEDINA A,AMER-HATEM F,AZAD A K,et al.Review on ammonia as a potential fuel:From synthesis to economics[J].Energy & Fuels,2021,35(9):6964-7029.
• [6] PELLOW M A,EMMOTT C J M,BARNHART C J,et al.Hydrogen or batteries for grid storage?A net energy analysis[J].Energy & Environmental Science,2015,8(7):1938-1952.
• [7] 刘伯峥，王静波，曾涛，等.磷酸铁锂电池寿命初期与末期安全性差异[J].化工学报，2022,73(12):5555-5563.LIU Bozheng,WANG Jingbo,ZENG Tao,et al.Safety differences of LiFePO4 batteries at the beginning of life and end of life[J].CIESC Journal,2022,73(12):5555-5563.
• [8] 李明飞，饶睦敏，孙婉妹，等.基于多孔介质模化的大容量电池储能热管理系统性能分析方法[J].储能科学与技术，2022,11(8):2526-2536.LI Mingfei,RAO Mumin,SUN Wanmei,et al.Analysis method based on porous medium modeling for thermal management system of large capacity battery energy storage[J].Energy Storage Science and Technology,2022,11(8):2526-2536.
• [9] ZHAO G,WANG X,NEGEVITSKY M,et al.A review of air-cooling battery thermal management systems for electric and hybrid electric vehicles[J].Journal of Power Sources,2021,501:230001.
• [10] JENA P.Materials for hydrogen storage:Past,present,and future[J].The Journal of Physical Chemistry Letters,2011,2(3):206-211.
• [11] 韩利，李琦，冷国云，等.氢能储存技术最新进展[J].化工进展，2022,41(S1):108-117.HAN Li,LI Qi,LENG Guoyun,et al.Latest research progress of hydrogen energy storage technology[J].Chemical Industry and Engineering Progress,2022,41(S1):108-117.
• [12] 周颖，周红军，徐春明.氢能的思考及发展路径判断和实践[J].化工进展，2022,41(8):4587-4592.ZHOU Ying,ZHOU Hongjun,XU Chunming.Exploration of the development path for the hydrogen energy[J].Chemical Industry and Engineering Progress,2022,41(8):4587-4592.
• [13] LIU M,YAO Z,GU J,et al.Issues and opportunities facing hydrolytic hydrogen production materials[J].Chemical Engineering Journal,2023,461:141911-141918.
• [14] HE T,PEI Q,CHEN P.Liquid organic hydrogen carriers[J].Journal of Energy Chemistry,2015,24(5):587-594.
• [15] SAIKIA T,PATIL S,SULTAN A.Hydrogen hydrate promoters for gas storage:A review[J].Energies,2023,16(6):2667.
• [16] 张振扬，妙丛，王峰，等.规模化氢液化装置现状及未来技术路线分析[J].化工进展，2022,41(12):6261-6274.ZHANG Zhenyang,MIAO Cong,WANG Feng,et al.Analysis of present status and future technical route on large-scale hydrogen liquefaction plant[J].Chemical Industry and Engineering Progress,2022,41(12):6261-6274.
• [17] DILLMAN K J,HEINONEN J.A ′just′ hydrogen economy:A normative energy justice assessment of the hydrogen economy[J].Renewable and Sustainable Energy Reviews,2022,167:112648.
• [18] CHAI W S,BAO Y,JIN P,et al.A review on ammonia,ammonia-hydrogen and ammonia-methane fuels[J].Renewable and Sustainable Energy Reviews,2021,147:111254.
• [19] VAN DER Spek M,BANET C,BAUER C,et al.Perspective on the hydrogen economy as a pathway to reach net-zero CO2 emissions in Europe[J].Energy & Environmental Science,2022,15(3):1034-1077.
• [20] LEE S,KIM T,HAN G,et al.Comparative energetic studies on liquid organic hydrogen carrier:A net energy analysis[J].Renewable and Sustainable Energy Reviews,2021,150:111447.
• [21] 王月姑，周梅，王兆林，等.以氨燃料为介质的全生命周期储能效率估算[J].储能科学与技术，2018,7(2):301-308.WANG Yuegu,ZHOU Mei,WANG Zhaolin,et al.Life-cycle energy efficiency estimition of large-scale ammonia fuel energy storage system[J].Energy Storage Science and Technology,2018,7(2):301-308.
• [22] DERMüHL S,RIEDEL U.A comparison of the most promising low-carbon hydrogen production technologies[J].Fuel,2023,340:127478.
• [23] 黄格省，李锦山，魏寿祥，等.化石原料制氢技术发展现状与经济性分析[J].化工进展，2019,38(12):5217-5224.HUANG Gesheng,LI Jinshan,WEI Shouxiang,et al.Status and economic analysis of hydrogen production technology from fossil raw materials[J].Chemical Industrial and Enginering Progress,2019,38(12):5217-5224.
• [24] 孙旭东，成雪蕾，王树萌，等.我国新能源风光发电制氢成本动态测算[J].洁净煤技术，2023,29(6):1-10.SUN Xudong,CHENG Xuelei,WANG Shuyin,et al.Dynamic cost analysis of hydrogen production from wind power and photovoltaic power[J].Clean Coal Technology,2023,29(6):1-10.
• [25] 张轩，樊昕晔，吴振宇，等.氢能供应链成本分析及建议[J].化工进展，2022,41(5):2364-2371.ZHANG Xuan,FAN Xinye,WU Zhenyu,et al.Hydrogen energy supply chain cost analysis and suggestions[J].Chemical Industrial and Enginering Progress,2022,41(5):2364-2371.
• [26] 徐世阳，张敏，朱亚军.变压吸附技术在焦炉煤气制氢中的应用[J].辽宁化工，2006,35(7):410-412.XU Shiyang,ZHANG Min,ZHU Yajun.Application of the pressure shift absorbing technique in hydrogen generation of COG[J].Liaoning Chemical Industry,2006,35(7):410-412.
• [27] REN L,ZHOU S,OU X.The carbon reduction potential of hydrogen in the low carbon transition of the iron and steel industry:The case of China[J].Renewable and Sustainable Energy Reviews,2023,171:113026.
• [28] GLENK G,REICHELSTEIN S.Economics of converting rene-wable power to hydrogen[J].Nature Energy,2019,4(3):216-222.
• [29] LI J,ZHU X,DJILALI N,et al.Comparative well-to-pump assessment of fueling pathways for zero-carbon transportation in China:Hydrogen economy or methanol economy?[J].Renewable and Sustainable Energy Reviews,2022,169:112935.
• [30] TERLOUW T,BAUER C,MCKENNA R,et al.Large-scale hydrogen production via water electrolysis:A techno-economic and environmental assessment[J].Energy & Environmental Science,2022,15(9):3583-3602.
• [31] 胡兵，徐立军，何山，等.碳达峰与碳中和目标下PEM电解水制氢研究进展[J].化工进展，2022,41(9):4595-4604.HU Bing,XU Lijun,HE Shan,et al.Researching progress of hydrogen production by PEM water electrolysis under the goal of carbon peak and carbon neutrality[J].Chemical Industrial and Enginering Progress,2022,41(9):4595-4604.
• [32] 王培灿，万磊，徐子昂，等.碱性膜电解水制氢技术现状与展望[J].化工学报，2021,72(12):6161-6175.WANG Peican,WAN Lei,XU Ziang,et al.Hydrogen production based-on anion exchange membrane water electrolysis:A critical review and perspective[J].CIESC Journal,2021,72(12):6161-6175.
• [33] FARRELL N.Policy design for green hydrogen[J].Renewable and Sustainable Energy Reviews,2023,178:113216.
• [34] PASTORE L M,LO Basso G,SFORZINI M,et al.Technical,economic and environmental issues related to electrolysers capacity targets according to the Italian Hydrogen Strategy:A critical analysis[J].Renewable and Sustainable Energy Reviews,2022,166:112685.
• [35] 高正平，涂安琪，李天新，等.面向零碳电力的氨燃烧技术研究进展[J].洁净煤技术，2022,28(3):173-184.GAO Zhengping,TU Anqi,LI Tianxin,et al.Recent advances on ammonia combustion technology for zero-carbon power[J].Clean Coal Technology,2022,28(3):173-184.
• [36] 王红霞，徐婉怡，张早校.可再生电力电解制绿色氢能的发展现状与建议[J].化工进展，2022,41(S1):118-131.WANG Hongxia,XU Wanyi,ZHANG Zaoxiao.Development status and suggestions of green hydrogen energy produced by water electrolysis from renewable energy[J].Chemical Industrial and Enginering Progress,2022,41(S1):118-131.
• [37] 段伦博，李天新.氨燃烧特性及稳燃技术研究进展[J].华中科技大学学报(自然科学版),2022,50(7):41-54.DUAN Lunbo,LI Tianxin.Research progress of ammonia combustion characteristic and stable-combustion technology[J].Journal of Huazhong University of Science and Technology Nature Science Edition,2022,50(7):41-54.
• [38] 张媛媛，赵静，鲁锡兰，等.有机液体储氢材料的研究进展[J].化工进展，2016,35(9):2869-2874.ZHANG Yuanyuan,ZHAO Jing,LU Xilan,et al.Progress in liquid organic hydrogen storage materials[J].Chemical Industrial and Enginering Progress,2016,35(9):2869-2874.
• [39] 孙晓明，沙琪昊，王陈伟，等.用于甲醇重整制氢的铜基催化剂研究进展[J].化工学报，2021,72(12):5975-6001.SUN Xiaoming,SHA Qihao,WANG Chenwei,et al.Application of copper-based catalysts for hydrogen production in methanol steam reforming[J].CIESC Journal,2021,72(12):5975-6001.
• [40] BAMPAOU M,HAAG S,KYRIAKIDES A S,et al.Optimizing methanol synthesis combining steelworks off-gases and renewable hydrogen[J].Renewable and Sustainable Energy Reviews,2023,171:113035.
• [41] MONDAL S,CHATTARAJ P K.Aromatic clusters and hydrogen storage[J].Energies,2023,16(6):2833.
• [42] HUANG J,BALCAMBE P,FENG Z.Technical and economic analysis of different colours of producing hydrogen in China[J].Fuel,2023,337:127227.
• [43] RAHMANI M,MOKHTARANI B,RAHMANIAN N.High pressure adsorption of hydrogen sulfide and regeneration ability of ultra-stable Y zeolite for natural gas sweetening[J].Fuel,2023,343:127937.
• [44] HASSAN I A,RAMADAN H S,SALEH M A,et al.Hydrogen storage technologies for stationary and mobile applications:Review,analysis and perspectives[J].Renewable and Sustainable Energy Reviews,2021,149:111311.
• [45] FOERG W.History of cryogenics:The epoch of the pioneers from the beginning to the year 1911[J].International Journal of Refrigeration,2002,25:283-292.
• [46] GENOVESE M,CIGOLOTTI V,JANNELLI E,et al.Hydrogen refueling process:Theory,modeling,and in-force applications[J].Energies,2023,16(6):2890.
• [47] AL GHAFRI S Z S,MUNRO S,CARDELLA U,et al.Hydrogen liquefaction:A review of the fundamental physics,engineering practice and future opportunities[J].Energy & Environmental Science,2022,15(7):2690-2731.
• [48] 曹军文，覃祥富，耿嘎，等.氢气储运技术的发展现状与展望[J].石油学报(石油加工),2021,37(6):1461-1478.CAO Junwen,QIN Xiangfu,GENG Ga,et al.Current status and prospects of hydrogen storage and transportation technology[J].Acta Petrolei Sinica (Petroleum Processing Section),2021,37(6):1461-1478.
• [49] 王昊成，杨敬瑶，董学强，等.氢液化与低温高压储氢技术发展现状[J].洁净煤技术，2023,29(3):102-113.WANG Haocheng,YANG Jingyao,DONG Xueqiang,et al.Review on hydrogen liquefaction and cryo-compression hydrogen storage technologies[J].Clean Coal Technology,2023,29(3):102-113.
• [50] 陈晓露，刘小敏，王娟，等.液氢储运技术及标准化[J].化工进展，2021,40(9):4806-4814.CHEN Xiaolu,LIU Xiaomin,WANG Juan,et al.Technology and standardization of liquid hydrogen storage and transportation[J].Chemical Industrial and Enginering Progress,2021,40(9):4806-4814.
• [51] ZOU A,ZENG Y,LUO E.New generation hydrogen liquefaction technology by transonic two-phase expander[J].Energy,2023,272:127150.
• [52] BRACHA M,LORENZ G,PATZELT A,et al.Large-scale hydrogen liquefaction in Germany[J].International Journal of Hydrogen Energy,1994,19(1):53-59.
• [53] 陈伟锋，尚娟，邢百汇，等.关于天然气管网安全掺氢比10%的商榷[J].化工进展，2022,41(3):1487-1493.CHEN Weifeng,SHANG Juan,XING Baihui,et al.Discussion on 10% as a safe ratio of hydrogen mixing into natural gas grids[J].Chemical Industrial and Enginering Progress,2022,41(3):1487-1493.
• [54] DAVIS M,OKUNLOLA A,DI LULLO G,et al.Greenhouse gas reduction potential and cost-effectiveness of economy-wide hydrogen-natural gas blending for energy end uses[J].Renewable and Sustainable Energy Reviews,2023,171:112962.
• [55] 尚娟，鲁仰辉，郑津洋，等.掺氢天然气管道输送研究进展和挑战[J].化工进展，2021,40(10):5499-5505.SHANG Juan,LU Yanghui,ZHENG Jinyang,et al.Research status-in-situ and key challenges in pipeline transportation of hydrogen-natural gas mixtures[J].Chemical Industrial and Enginering Progress,2021,40(10):5499-5505.
• [56] SILVESTRE I,PASTOR R,NETO R C.Power losses in natural gas and hydrogen transmission in the Portuguese high-pressure network[J].Energy,2023,272:127136.
• [57] 郭秀盈，李先明，许壮，等.可再生能源电解制氢成本分析[J].储能科学与技术，2020,9(3):688-695.GUO Xiuying,LI Xianming,XU Zhuang,et al.Cost analysis of hydrogen production by electrolysis of renewable energy[J].Energy Storage Science and Technology,2020,9(3):688-695.
• [58] 董存，梁志峰，礼晓飞，等.跨区特高压直流外送优化提升新能源消纳能力研究[J].中国电力，2019,52(4):41-50.DONG Cun,LIANG Zhifeng,LI Xiaofei,et al.Study on power optimization of the trans-regional UHVDC delivery channels in promoting renewable energy accommodation capacity[J].Electric Power,2019,52(4):41-50.
• [59] 牛涛，张文振，刘欣，等.燃煤锅炉氨煤混合燃烧工业尺度试验研究[J].洁净煤技术，2022,28(3):193-200.NIU Tao,ZHANG Wenzhen,LIU Xin,et al.Industrial-scale experiment investigation of ammonia-coal cofiring in coal fired boiler[J].Clean Coal Technology,2022,28(3):193-200.
• [60] 牛涛，张文振，魏书洲，等.不同空气分级模式下氨煤掺烧数值模拟[J].洁净煤技术，2023,29(9):145-151.NIU Tao,ZHANG Wenzhen,WEI Shuzhou,et al.Modeling co-firing ammonia with coal in differeng air staging modes[J].Clean Coal Technology,2023,29(9):145-151.
• [61] 徐连兵，陈璟，魏书洲，等.大比例掺氨下煤粉火焰区喷氨对燃烧及NO生成特性的影响[J].洁净煤技术，2023,29(9):134-144.XU Lianbing,CHEN Jing,WEI Shuzhou,et al.Effect of ammonia injection location in the pulverized-coal flame zone on combustion and NO formation characteristics under large proportion of ammonia blending conditions[J].Clean Coal Technology,2023,29(9):134-144.
• [62] 滕欣余，张国华，胡辰树，等.我国典型城市氢能经济性和低成本氢源探索分析[J].化工进展，2022,41(12):6295-6301.TENG Xinyu,ZHANG Guohua,HU Chenshu,et al.Analysis on hydrogen energy economy and low cost of hydrogen source in typical cities of China[J].Chemical Industrial and Enginering Progress,2022,41(12):6295-6301.
• [63] MOHIDEEN M M,SUBRAMANIAN B,SUN J,et al.Techno-economic analysis of different shades of renewable and non-renewable energy-based hydrogen for fuel cell electric vehicles[J].Renewable and Sustainable Energy Reviews,2023,174:113153.
• [64] GRUBE T,DORé L,HOFFRICHTER A,et al.An option for stranded renewables:Electrolytic-hydrogen in future energy systems[J].Sustainable Energy & Fuels,2018,2(7):1500-1515.
• [65] CESARO Z,IVES M,LUKE R N,et al.Ammonia to power:Forecasting the levelized cost of electricity from green ammonia in large-scale power plants[J].Applied Energy,2021,282:116009.
• [66] 张微.制氢技术进展及经济性分析[J].当代石油石化，2022,30(7):31-36.ZHANG Wei.The Progress and economic analysis of hydrogen production technology[J].Petroluem & Petrochemical Today,2022,30(7):31-36.
• [67] 王盼.基于平准化成本的绿氢产业经济性研究[J].石油石化绿色低碳，2023,8(2):1-9.WANG Pan.Study on economy of green hydrogen industry based on levelized cost[J].Green Petroluem & Petrochemicals,2023,8(2):1-9.
• [68] RODRIGUEZ C A,MODESTINO M A,PSALTIS D,et al.Design and cost considerations for practical solar-hydrogen generators[J].Energy Environment Science,2014,7(12):3828-3835.
• [69] WAGNER K,TIWARI P,SWIEGERS G F,et al.Alkaline fuel cells with novel Gortex-based electrodes are powered remarkably efficiently by methane containing 5% hydrogen[J].Advanced Energy Materials,2017,8(7):1702285.
• [70] 罗佐县，曹勇.氢能产业发展前景及其在中国的发展路径研究[J].中外能源，2020,25(2):9-15.LUO Zuoxian,CAO Yong.Development prospect of hydrogen energy industry and its development path in China[J].Sino-Global Energy,2020,25(2):9-15.
• [71] 赵运林，曹田田，张成晓，等.集中式制氢技术进展及成本分析[J].石油炼制与化工，2022,53(10):122-126.ZHAO Yunlin,CAO Tiantian,ZHANG Chengxiao,et al.Progress and cost analysis of centralized hydrogen production technology[J].Petroluem Processing and Petrochemicals,2022,53(10):122-126.
• [72] 蒋珊.绿氢制取成本预测及与灰氢、蓝氢对比[J].石油石化绿色低碳，2022,7(2):6-11.JIANG Shan.Cost prediction:Green hydrogen VS grey/blue hydrogen[J].Green Petroluem & Petrochemicals,2022,7(2):6-11.
• [73] HREN R,VUJANOVI■,VAN FAN Y,et al.Hydrogen production,storage and transport for renewable energy and chemicals:An environmental footprint assessment[J].Renewable and Sustainable Energy Reviews,2023,173:113113.
• [74] REUB M,GRUBE T,ROBINIUS M,et al.Seasonal storage and alternative carriers:A flexible hydrogen supply chain model[J].Applied Energy,2017,200:290-302.
• [75] ZHANG T,URATANI J,HUANG Y,et al.Hydrogen lique-faction and storage:Recent progress and perspectives[J].Renewable and Sustainable Energy Reviews,2023,176:113204.
• [76] CHATTERJEE S,PARSAPUR R K,HUANG K.Limitations of ammonia as a hydrogen energy carrier for the transportation sector[J].ACS Energy Letters,2021,6(12):4390-4394.
• [77] R M,P A.Ammonia as a feedstock for a hydrogen fuel cell;reformer and fuel cell behaviour[J].Journal of Power Sources,1994,49(1-3):271-282.
• [78] KRASAE-IN S,STANG J H,NEKSA P.Exergy analysis on the simulation of a small-scale hydrogen liquefaction test rig with a multi-component refrigerant refrigeration system[J].International Journal of Hydrogen Energy,2010,35(15):8030-8042.
• [79] 中国气体工业协会.《国内外液氢发展调研》[EB/OL].(2021-03-26)[2023-09-18].http://www.cigia.org.cn/?m=home&c=View&a=index&aid=5097.
• [80] 丁镠，唐涛，王耀萱，等.氢储运技术研究进展与发展趋势[J].天然气化工-C1化学与化工，2022,47(2):35-40.DING Liao,TANG Tao,WANG Yaoxuan,et al Research progress and development trend of hydrogen storage and transportation technology[J].Natural Gas Chemical Industry,2022,47(2):35-40.
• [81] 王集杰，韩哲，陈思宇，等.太阳燃料甲醇合成[J].化工进展，2022,41(3):1309-1316.WANG Jijie,HAN Zhe,CHEN Siyu,et al.Liquid sunshine methanol[J].Chemical Industrial and Enginering Progress,2022,41(3):1309-1316.
• [82] MBATHA S,EVERSON R C,MUSYOKA N M,et al.Power-to-methanol process:A review of electrolysis,methanol catalysts,kinetics,reactor designs and modelling,process integration,optimisation,and techno-economics[J].Sustainable Energy & Fuels,2021,5(14):3490-3569.
• [83] 势银能链.《绿氢应用于甲醇工业的情景和路径调研报告》[EB/OL].(2021-11-03)[2023-09-18].http://www.trendbank.net/.
• [84] HANK C,GELPKE S,SCHNABL A,et al.Economics & carbon dioxide avoidance cost of methanol production based on renewable hydrogen and recycled carbon dioxide – power-to-methanol[J].Sustainable Energy & Fuels,2018,2(6):1244-1261.
• [85] 势银能链.《绿氢应用于甲醇和合成氨工业的情景和路径》[EB/OL].(2022-01-15)[2023-09-18].http://www.trendbank.net/.
• [86] SALMON N,BA■áNTARA R.Green ammonia as a spatial energy vector:A review[J].Sustainable Energy & Fuels,2021,5(11):2814-2839.
• [87] SCHüTH F,PALKOVITS R,SCHL?GL R,et al.Ammonia as a possible element in an energy infrastructure:Catalysts for ammonia decomposition[J].Energy Environment Science,2012,5(4):6278-6289.
• [88] HANK C,STEMBERG A,K?PPEL N,et al.Energy efficiency and economic assessment of imported energy carriers based on renewable electricity[J].Sustainable Energy & Fuels,2020,4(5):2256-2273.
• [89] ISHIMOTO Y,VOLDSUND M,NEKSá P,et al.Large-scale production and transport of hydrogen from Norway to Europe and Japan:Value chain analysis and comparison of liquid hydrogen and ammonia as energy carriers[J].International Journal of Hydrogen Energy,2020,45(58):32865-32883.
• [90] R M,P A.Comparison of ammonia and methanol applied indirectly in a hydrogen fuel cell[J].International Journal of Hydrogen Energy,1994,19(6):535-542.
• [91] REUB M,DIMOS P,LéON A,et al.Hydrogen road transport analysis in the energy system:A case study for Germany through 2050[J].Energies,2021,14(11):3166.
• [92] 单彤文，宋鹏飞，李又武，等.制氢、储运和加注全产业链氢气成本分析[J].天然气化工-C1化学与化工，2020,45(1):85-96.SHAN Tongwen,SONG Pengfei,LI Youwu,et al.Cost analysis of hydrogen from the perspective of the whole industrial chain of production,storage,transportation and refueling[J].Natural Gas Chemical Industry,2020,45(1):85-96.
• [93] ARMIJO J,PHILIBERT C.Flexible production of green hydrogen and ammonia from variable solar and wind energy:Case study of Chile and Argentina[J].International Journal of Hydrogen Energy,2020,45(3):1541-1558.
• [94] HE X,SHU B,NASCIMENTO D,et al.Auto-ignition kinetics of ammonia and ammonia/hydrogen mixtures at intermediate temperatures and high pressures[J].Combustion and Flame,2019,206:189-200.
• [95] KOBAYASHI H,HAYAKAWA A,SOMARATHNE K D K A,et al.Science and technology of ammonia combustion[J].Proceedings of the Combustion Institute,2019,37(1):109-133.
• [96] TAMURA M,GOTOU T,ISHII H,et al.Experimental investigation of ammonia combustion in a bench scale 1.2 MW-thermal pulverised coal firing furnace[J].Applied Energy,2020,277:115580.
• [97] 王一坤，邓磊，陈钢，等.燃煤机组耦合氢基衍生燃料发电对机组影响分析[J].洁净煤技术，2022,28(6):54-64.WANG Yikun,DENG Lei,CHEN Gang,et al.Influence of large-scale coupled hydrogen derived fuel power generation on coal fired units[J].Clean Coal Technology,2022,28(6):54-64.
• [98] 闫卫东，秦世泰，杨凯，等.氨-煤在沉降炉中掺烧试验及氨的氧化动力学[J].洁净煤技术，2023,29(9):127-133.YAN Weidong,QIN Shitai,YANG Kai,et al.Experiment of ammonia-coal co-firing in a drop tube furnace and the kinetic modeling of ammonia oxdation[J].Clean Coal Technology,2023,29(9):127-133.
• [99] ZAMFIRESCU C,DINCER I.Ammonia as a green fuel and hydrogen source for vehicular applications[J].Fuel Processing Technology,2009,90(5):729-737.
• [100] SUN S,JIANG Q,ZHAO D,et al.Ammonia as hydrogen carrier:Advances in ammonia decomposition catalysts for promising hydrogen production[J].Renewable and Sustainable Energy Reviews,2022,169:11