苗强
Miao Qiang

• 1:北京低碳清洁能源研究所

摘要(Abstract)：

为了总结脱硝技术的研究成果,找出脱硝技术的发展趋势,创建我国具有自主知识产权的脱硝技术体系,分析了国内外脱硝技术的现状,介绍了干法和湿法烟气脱硝技术的各种工艺,指出现阶段技术最成熟的脱硝工艺是选择性催化还原(SCR),但选择性非催化还原(SNCR)、等离子体、氧化和吸收等工艺也具有非常好的前景。研究了大量脱硝技术的特点,指出作为脱硝主流技术的SCR工艺研究将集中在优化工艺流程、研发高性能SCR催化剂、SCR催化剂寿命延长和再生技术;基于不同脱硝机理的不同脱硝工艺的结合或联用是脱硝技术的一个重要发展方向;加大研发联合脱硝和脱硫的工艺;创新脱硝机理、多级或多段复合脱硝工艺以及可再生循环使用的新型脱硝催化剂和吸附剂将成为研究热点。
In order to summarize the research achievements and elucidate the development trend of denitration techniques,as well as to establish a systematic denitration technology with proprietary intellectual property rights in China,this paper overviewed the current progress of domestic and foreign denitration techniques,and introduced several typical dry and wet processes of flue gas denitration technology.Accordingly,the most mature denitration process is the selective catalytic reduction denitration( SCR) process,while the selective non catalytic reduction( SNCR),plasma technology,oxidation and absorption processes also have a certain prospect and potential. As the mainstream denitration process,the improvement of SCR technique will mainly focus on the process optimization,high performance SCR catalyst development,catalyst life extension,and catalyst regeneration. The combination or integration of different denitriation processes based on different mechanisms is one of the important developing directions of denitration technology,and the process combining denitration and desulfurization processes should be researched.The innovation of denitration mechanism,integration of multi-stage or multi section,and development of novel recycling and regenerating denitration catalyst and adsorbents will become hot topics in this field.

关键词(KeyWords)： 脱硝;SCR;SNCR;氨;活性炭;吸收;氧化;液相络合
denitration;SCR;SNCR;ammonia;activated carbon;absorption;oxidation;liquid phase complexation

Abstract:

Keywords:

基金项目(Foundation): 国家高技术研究发展计划(863计划)资助项目(2012AA06A115)

作者(Author): 苗强
Miao Qiang

DOI: 10.13226/j.issn.1006-6772.2017.02.003

参考文献(References)：

• [1]王刻文,胡敏,郭宏昶,等.催化烟气脱硝工艺选择探讨[J].山东化工,2013,42(10):213-217.Wang kewen,Hu Min,Guo Hongchang,et al.Probe into FCCU flue gas de NOxprocess selection[J].Shandong Chemical Industry,2013,42(10):213-217.
• [2]江苏大峘集团有限公司.基于煤粉低氧燃烧技术的中温低氧含量热风炉:103940080[P].2014-07-23.
• [3]中节环(北京)环境科技股份有限公司.大空间空气分级燃烧锅炉:204494379U[P].2015-07-22.
• [4]武汉明正动力工程有限公司.一种燃料分级燃烧低NOx燃烧器:204513378U[P].2015-07-29.
• [5]山西蓝天环保设备有限公司.带有烟气再循环的特殊循环流化床锅炉:104456545[P].2015-03-25.
• [6]上海交通大学.一种低NOx气体燃料燃烧器和燃烧方法:104791792[P].2015-07-22.
• [7]集美大学.新型旋流浓淡煤粉燃烧器:104832918[P].2015-08-12.
• [8]中国计量学院.一种耦合空气分级和燃料分级低NOx四拱型W火焰锅炉:104406160[P].2015-03-11.
• [9]山东大学.一种烟气再循环和超细煤粉再燃的层燃炉及其燃烧工艺:1053117453[P].2016-03-09.
• [10]深圳市中创达热工技术有限公司.一种高温低氧燃烧装置:1039611409[P].2014-11-06.
• [11]Wendt J O L,Linak W P,Groff P W,et al.Hybrid SNCR-SCR technologies for NOxcontrol:Modeling and experiment[J].AICh E Journal,2001,47(11):2603-2617.
• [12]中国华能集团清洁能源技术研究院有限公司.一种适用于循环流化床锅炉的液氨法SNCR脱硝系统:104764035[P].2015-07-08.
• [13]太仓东能环保设备有限公司.一种SNCR-SCR烟气脱硝工艺:105214456[P].2016-01-06.
• [14]高洁.国内外目前具有研究价值的烟气脱硝技术[J].科技信息,2010(7):360-363.Gao Jie.Present domestic and foreign flue gas denitration technology with research value[J].Science&Technology Information,2010(7):360-363.
• [15]顾庆华,胡秀丽.SCR脱硝反应区域运行温度影响因素研究[J].洁净煤技术,2015,21(2):77-80.Gu Qinghua,Hu Xiuli.Influencing factors of operating temperature of denitration SCR reactor[J].Clean Coal Technology,2015,21(2):77-80.
• [16]史建公,刘志坚,张毅,等.SCR脱硝催化剂国内专利技术进展[J].中外能源,2013,18(5):65-78.Shi Jiangong,Liu Zhijian,Zhang Yi,et al.Domestic patent technology progress of SCR denitration catalyst[J].Sino-Global Energy,2013,18(5):65-78.
• [17]北京科技大学.一种烟气脱硝催化剂的制备方法:102247834[P].2012-12-19.
• [18]广东电网有限责任公司电力科学研究院.一种SCR脱硝催化剂及其制备方法以及用途:105195170[P].2015-12-30.
• [19]王天泽,楚英豪,郭家秀,等.烟气脱硝技术应用现状与研究进展[J].四川环境,2012,31(3):106-110.Wang Tianze,Chu Yinghao,Guo Jiaxiu,et al.Status quo of application and development of flue gas denitration technology[J].Sichuan Environment,2012,31(3):106-110.
• [20]北京国电龙源环保工程有限公司.一种选择性植入活性成分的废弃脱硝催化剂的再生方法:105536884[P].2016-05-04.
• [21]艾淑艳.活性焦脱硝工艺系统:202778203U[P].2013-03-13.
• [22]傅月梅,潘敏,张九杉,等.活性焦烟气脱硝影响因素研究[J].洁净煤技术,2015,21(4):122-124,129.Fu Yuemei,Pan Min,Zhang Jiushan,et al.Influencing factors of denitrification technology by activated coke[J].Clean Coal Technology,2015,21(4):122-124,129.
• [23]赵毅,韩钟国,韩颖慧,等.干法烟气同时脱硫脱硝技术的应用及新进展[J].工业安全与环保,2009,35(2):4-6.Zhao Yi,Han Zhongguo,Han Yinghui,et al.Applications and new progress in simultaneous desulfurization and denitrification by dry flue gas control technology[J].Industrial Safety and Environmental Protection,2009,35(2):4-6.
• [24]王佳,王孝敏,张妍,等.烧煤烟气脱硫脱硝新技术的发展及应用[J].平顶山学院学报,2016,31(2):54-59.Wang Jia,Wang Xiaomin,Zhang Yan,et al.Development and application on new technology for desulfurization and denitration of coal fired flue gas[J].Journal of Pingdingshan University,2016,31(2):54-59.
• [25]张虎,佟会玲,王晋元,等.用KMNO4调质钙基吸收剂从燃煤烟气同时脱硫脱硝[J].化工学报,2007,58(7):1810-1815.Zhang Hu,Tong Huiling,Wang Jinyuan,et al.Simultaneous removal of SO2and NO by using calcium absorbent with KMn O4as additive[J].Journal of Chemical Industry and Engineering,2007,58(7):1810-1815.
• [26]Sara E,Kumazawa H,Kudo I,et al.Absorption of lean NOxin aqueous solution of Na Cl O2and Na OH[J].Industrial&Engineering Chemistry Process Design and Development,1979,18(2):275-278.
• [27]Thomas D,Vanderschuren J.Effect of temperature on NOxabsorption into nitrite acid solutions containing hydrogen peroxide[J].Industry Engeering Chemical Research,1998,37(11):4418-4423.
• [28]刘国庆.臭氧低温氧化脱硝工艺及系统:105854554[P].2016-08-17.
• [29]马乐凡,童志权.液相络合-铁粉还原-酸吸收回收法脱除烟气中NOx[J].环境科学研究,2005,18(5):63-66.Ma Lefan,Tong Zhiquan.Removal of NOxfrom flue gas with the recovery process of absorption with acid following complexation in aqueous solution and reduction with iron powder[J].Research of Environmental Sciences,2005,18(5):63-66.
• [30]张金龙,辛志玲,张大全.湿法烟气脱硝技术研究进展[J].上海电力学院学报,2010,26(2):151-156.Zhang Jinlong,Xin Zhiling,Zhang Daquan.Research progress of wet flue gas denitrification technology[J].Journal of Shanghai University of Electric Power,2010,26(2):151-156.
• [31]广州特种承压设备检测研究院.一种还原与氧化联合脱硝系统及其脱硝方法:105251326[P].2016-01-20.
• [32]王跃.燃煤电厂烟气脱硝技术概述[J].广东化工,2015,42(14):122-123.Wang Yue.The overview of flue gas denitrification technology of coal-fired power plant[J].Guangdong Chemical Industry,2015,42(14):122-123.
• [33]潘光,李恒庆,卢守舟,等.烟气脱硝技术及在我国的应用[].中国环境管理干部学院学报,2008,18(1):90-93.Pan Guang,Li Hengqing,Lu Shouzhou,et al.Flue gas de-NOx technology and its application in China[].Journal of Environmental Management College of China,2008,18(1):90-93.
• [34]蒋克旭.一种碱吸收液可循环利用的烟气净化方法:103585869[P].2014-02-19.
• [35]洛阳安德路石化设备有限公司.一种同时脱硫脱硝活性炭干法烟气净化装置:204841411U[P].2015-12-09.
• [36]南京白云化工环境监测有限公司.一种烟气脱硫脱硝系统:105148697[P].2015-12-16.
• [37]东南大学.吸附-低温等离子体同步脱硫脱硝装置及其方法:1772347[P].2006-05-17.
• [38]洪燕,赵培超,蒋建华,等.干法脱硝技术:清洁高效燃煤发电技术协作网2008年会论文集[C].南京:清洁高效燃煤发电技术协作网,2008:1-3.
• [39]Hitchins J,Morawska L,Wolff R,et al.Concentrations of submicrometre particles from vehicle emissions near a major road[J].Atmospheric Environment,2000,34(1):51-59.
• [40]Janssen N,Vanmansom D,Wanderjagt K,et al.Mass concentration and elemental composition of airborne particulate matter at street and background locations[J].Atmospheric Environment,1997,31(8):1185-1193.
• [41]中国科学院上海应用物理研究所.电子束烟气脱硫脱硝的方法及其装置:1762551[P].2006-04-26.
• [42]杭州西堡环境科技有限公司.低温等离子脱硫脱硝系统:205627560U[P].2016-10-12.
• [43]东南大学.喷射鼓泡法用烟气脱硫脱硝吸收液:1128003[P].2003-11-19.
• [44]沈阳汇川环境工程有限公司.一种燃煤烟气脱硝脱硫方法:105879642[P].2016-08-24.