Wang Xianghui;Men Zhuowu;Lyu Yijun;Li Yonglong;National Institute of Clean-and-Low-Carbon Energy;Fischer-Tropsch synthesis process,which has gradually entered the industrialization operation stage,is the key technology of indirect coal liquefaction process and an important direction of clean coal utilization technology.The development of catalyst with high activity,high selectivity and high stability is one of the key factors of the success of Fischer- Tropsch synthesis technology. Catalyst reduction process is an important process to obtain high performance catalysts,and the study of the reduction mechanism and reduction kinetics is the key issue to the process development. This paper introduced the research progress of reduction mechanism and reduction kinetics of Fischer-Tropsch synthesis catalysts,and discussed the effect of the calcination temperature,reducing atmosphere,reducing pressure and water partial pressure on the reduction mechanism and reduction kinetics.With the increase of calcination temperature of the catalyst,the superparamagnetic magnetic Fe~(3+) phase transforms to paramagnetic magnetic α-Fe_2O_3 phase,the lattice defects decreases,grain size increases,the activation energy and pre-exponential factor increases and the reducing ability of the catalyst decreases. With the increase of the partial pressure of CO in the reducing atmosphere,the degree of reduction and carbonization of the catalyst increases,more active centers forms on the surface of the catalyst,and the reducing ability of the catalyst increases.The increase of the reduction pressure promotes the reduction and carbonization of the catalyst,but the higher reduction pressure can inhibit the reduction and carbonization of the catalyst.The water pressure has no obvious effect on the reduction path of the catalyst,but the increase of water pressure can prevent the reduction of the catalyst,and the activation energy increases.According to the performance requirements to iron-based catalysts for Fischer-Tropsch synthesis technology,the research on catalyst reduction process should focus on the development of reduction process with middle temperature,syngas atmosphere and low pressure.It will reduce the investment and costs,shorten the reduction time,improve the catalytic activity and stability and improve the competitiveness of enterprises.
2017 02 v.23;No.108 [Abstract][OnlineView][HTML全文][Download 162K]