CO2在咸水层的地质封存及应用进展Review on CO2 geological storage in saline formations
朱佩誉
ZHU Peiyu
摘要(Abstract):
CO_2在咸水层(盐沼池构造)中的封存是地质封存技术中封存量最大、最有前景的途径。总结了咸水层中封存CO_2机理及其在工程应用方面的主要进展。咸水层中CO_2地质封存的俘获机理比较复杂,是由一系列物理和地球化学的俘获机理共同作用的结果。论述了CO_2在咸水层地质封存的主要封存机理,如构造地层封存机理、水力学封存机理、束缚气封存机理、溶解封存机理和矿物化封存机理。现有的CO_2地质封存项目的顺利运行证明了其在咸水层中封存技术上的可行性。CCUS技术成功应用于咸水层仍有许多问题需要解决,如地质封存项目广泛分布在全球不同地质条件,需要不同的监测技术、法律监管问题及经济效益评估。
Storing CO_2 in saline formations is the largest and most promising method for geological storage. The mechanism of CO_2 storage in saline formations and the main development in engineering applications were summarized. The complex mechanism of CO_2 storage in saline formations is the result of a combination of physical and chemical capture mechanisms.The mechanism of structural formation storage, hydraulic storage mechanism, irreducible gas storage mechanism, dissolution storage mechanism and mineralization storage mechanism were reviewed. Current CO_2 geological storage projects prove feasibility of CO_2 sealing in saline formations. However, there are still many issues remain to be resolved, such as different detection techniques under different geological conditions of worldwide geological storage projects, and there are also different regulation issues, while their economics are required to be further understood for deploying CCUS in saline formations successfully.
关键词(KeyWords):
CO_2;地质封存;咸水层;封存机理;封存能力
CO_2;geological storage;saline formation;trapping mechanism;storage capacity
基金项目(Foundation):
作者(Author):
朱佩誉
ZHU Peiyu
DOI: 10.13226/j.issn.1006-6772.21080204
参考文献(References):
- [1] JOS O,JEROEN P.Trends in global CO2 and total greenhouse gas emissions:2020 Report[R].[S.l.]:PBL Netherlands Environmental Assessment Agency,2020.
- [2] 米剑锋,马晓芳.中国CCUS技术发展趋势分析[J].中国电机工程学报,2019,39(9):2537-2544.
- [3] HEPBURN C,ADLEN E K,BEDDINGTON J,et al.The technological and economic prospects for CO2 utilization and removal[J].Nature,2019,575:87-97.
- [4] 蔡博峰,李琦,张贤,等.中国二氧化碳捕集利用与封存(CCUS)年度报告(2021)—中国CCUS 路径研究[R].生态环境部环境规划院,中国科学院武汉岩土力学研究所,21世纪议程管理中心,2021.
- [5] IPCC.Special report on carbon dioxide capture and storage[R].Cambidge:Cambridge University Press,2005.
- [6] BACHU S.Sequestration of CO2 in geological media:criteria and approach for site selection in response to climate change[J].Energy Conversion and Management,2000,41(9):953-970.
- [7] 仲平,彭斯震,贾莉,等.中国碳捕集、利用与封存技术研发与示范[J].中国人口·资源与环境,2011,21(12):41-45.
- [8] 李小春,张九天,李琦,等.中国碳捕集、利用与封存技术路线图(2011版)实施情况评估分析[J].科技导报,2018,36(4):85-95.
- [9] BACHU S,ADAMS J J.Sequestration of CO2 in geological media in response to climate change:Capacity of deep saline aquifers to sequester CO2 in solution [J].Energy Conversion & Management,2003,44(20):3151-3175.
- [10] 叶斌,叶为民.地下咸水层封存CO2的研究现状及展望[J].科技资讯,2012(36):66-69.
- [11] 李光,刘建军,刘强,等.二氧化碳地质封存研究进展综述[J].湖南生态科学学报,2016,3(4):41-48.
- [12] BACHU S.CO2,storage in geological media:Role,means,status and barriers to deployment[J].Progress in Energy and Combustion Science,2008,34(2):254-273.
- [13] 李琦,宋然然,匡冬琴,等.二氧化碳地质封存与利用工程废弃井技术的现状与进展[J].地球科学进展,2016,31(3):225-235.[13] SHUKLA R,RANJITH P,HAQUE A,et al.A review of studies on CO2,sequestration and caprock integrity[J].Fuel,2010,89(10):2651-2664.
- [14] BENSON S M,SURLES T.Carbondioxide capture and storage:An overview with emphasis on capture and storage in deep geological formations[J].Proceedings of the IEEE,2006,94(10):1795-1805.
- [15] LIU Q,MAROTO-VALER M M.Parameters affecting mineral trapping of CO2,sequestration in brines[J].Greenhouse Gases Science & Technology,2011,1(3):211-222.
- [16] ZHANG M,BACHU S.Review of integrity of existing wells in relation to CO2 geological storage:What do we know?[J].International Journal of Greenhouse Gas Control,2011,5(4):826-840
- [17] GUNTER W D,PERKINS E H,MCCANN T J.Aquifer disposal of CO2 -rich gases:Reaction design for added capacity[J].Energy Conversion & Management,1993,34(9/10/11):941-948.
- [18] KUMAR S,MANDAL A.A comprehensive review on chemically enhanced water alternating gas/CO2 (CEWAG)injection for enhanced oil recovery [J].Journal of Petroleum Science and Engineering,2017,157:696-715.
- [19] WINTER E M,BERGMAN P D.Availability of depleted oil and gas reservoirs for disposal of carbon dioxide in the United States[J].Energy Conversion & Management,1993,34(9/10/11):1177-1187.
- [20] MICHAEL K,GOLAB A,SHULAKOVA V,et al.Geological storage of CO2,in saline aquifers:A review of the experience from existing storage operations[J].International Journal of Greenhouse Gas Control,2010,4(4):659-667.
- [21] KIHM J H.Numerical simulation of impacts of mineralogical compositions on trapping mechanisms and efficiency of carbon dioxide injected into deep saline sandstone aquifers[J].Biochemical & Biophysical Research Communications,2013,440(3):393-398.
- [22] 许雅琴,张可霓,王洋.利用TOUGH2进行场地规模CO2地质封存的模拟方法[J].工程勘察,2012(3):37-43.
- [23] RANGANATHAN P,HEMERT P V,RUDOLPH E S J,et al.Numerical modeling of CO2 mineralisation during storage in deep saline aquifers[J].Energy Procedia,2011,4(4):4538-4545.
- [24] AUDIGANE P,GAUS I,CZERNICHOWSKI-LAURIOL I,et al.Two-dimensional reactive transport modeling of CO2 injection in a saline aquifer at the Sleipner site,North Sea[J].American Journal of Science,2011,307(7):699-704.
- [25] GCCSI.Global status of CCS 2021 [R].Australia:Melbourne,2021.
- [26] 杨红,赵习森,康宇龙,等.鄂尔多斯盆地CO2地质封存适宜性与潜力评价[J].气候变化研究进展,2019,15(1):95-102.
- [27] 吴秀章,崔永君.神华10万t/a CO2盐水层封存研究[J].石油学报(石油加工),2010,26(S1):236-239.
- [28] 杨国栋.鄂尔多斯盆地二氧化碳地质封存机理研究[D].武汉:中国地质大学,2015.
- [29] 张冰,梁凯强,王维波,等.鄂尔多斯盆地深部咸水层CO2有效地质封存潜力评价[J].非常规油气,2019,6(3):15-20.
- [30] 孙玉景,周立发,霍斐斐.鄂尔多斯盆地马家沟组马五1亚段地层水特征及对CO2地质封存的意义[J].地球环境学报,2019,10(1):49-57.